无机盐浓度和种类对静电破乳的影响.PDF

第27 卷第5 期 高 校 化 学 工 程 学 报 No.5 Vol.27 2013 年10 月 Journal of Chemical Engineering of Chinese Universities Oct. 2013 文章编号：1003-9015(2013)05-0755-06 无机盐浓度和种类对静电破乳的影响 孙治谦, 金有海, 王振波, 王 磊 ( 中国石油大学(华东) 化学工程学院 重质油国家重点实验室, 山东 青岛 266555) 摘 要：为探究静电聚结破乳机理，采用显微实验研究的方法，深入考察不同无机盐浓度和种类条件下 W/O 乳状液分 散相液滴在脉冲电场作用下的破乳聚并行为。实验发现，一定范围内，随溶于分散相无机盐浓度的增加，液滴电导率 增大，极化作用力增强，迁移聚并速率加快，沉降分离效果提升。无机盐浓度过高时，极化作用力、离子冲击力激增， 出现过度极化现象。电导率、界面张力、pH 值和介电常数差别不大的条件下，液滴的极化效果主要取决于离子极化效 应，高价盐的静电聚结速率显著增大。油水界面张力低、离子价位高的条件下，极易形成数量较多、长度极长的液链， 降低了液滴的迁移聚并速率。上述研究成果为高效紧凑的静电聚结设备的开发提供了依据。 关键词：无机盐；静电聚结；破乳；极化；脉冲 中图分类号：TE868 ；TE624.1 文献标识码：A DOI:10.3969/j.issn.1003-9015.2013.05.005 Impact of Type and Concentration of Inorganic Salt Acting on Electrostatic Demulsification Process SUN Zhi-qian, JIN You-hai, WANG Zhen-bo, WANG Lei (State Key Laboratory of Heavy Oil, College of Chemical Engineering, China University of Petroleum (East China), Qingdao 266555, China) Abstract: In order to investigate the mechanism of electrostatic coalescing demulsification, micro-experiment was carried out, and the demulsification and coalescing behavior of water droplets under the effect of impluse electric field in W/O emulsion with different inorganic salt type and concentration conditions was comprehensively studied. It was demonstrated that, with inorganic salt concentration increasing, electrical conductivity and polarization force of droplets increase, migrating and coalescing velocities speed up, sedimentation and separating effect raise to cer