流体化床Fenton深度处理合成制药废水研究.docVIP

流体化床Fenton深度处理合成制药废水研究 摘要：采用流体化床fenton装置深度处理合成制药废水，通过正交试验确定了处理合成制药废水的最佳条件是hrt为20min，初始ph值为4.0，h2o2/codcr（质量比）为4.0，h2o2/fe2+（摩尔比）为15，且在最佳条件下出水codcr 稳定在80mg/l 以下，可以达到《污水综合排放标准》（gb8979-1996）一级标准。同时将其与标准fenton氧化法进行对比试验，结果显示流体化床fentoncodcr去除率可提高13%以上，污泥产生量可降低70%，运行成本可减低28%，稳定运行成本可以控制在3.0元/吨废水以内。 关键词：流体化床fenton； 深度处理； 合成制药废水 中图分类号：x703 文献标识码：a 文章编号：1007-0370 (2012) 01-0118-04 study on the advanced treatment of  synthesis pharmaceutical wastewater by fluidized bed fenton  wang fuchao1, mei rongwu1, liu jun2  (1.environmental science research＆design institute of zhejiang province，hangzhou 310007; 2. school of construction engineering，zhejiang university of technology，hangzhou 310014) abstract： the fluidized-bed fenton reactor was employed for advanced treatment of synthesis pharmaceutical wastewater. through orthogonal tests, the best reaction conditions for synthesis pharmaceutical wastewater treatment were determined as 20 min of hrt, 4.0 of initial ph value, 4.0 of h2o2/codcr mass ratio and 15 of h2o2/fe2+ moore ratio. under those optimum conditions, codcr concentration of the effluent was detected stably below 80 mg/l, which complies with the class a of integrated wastewater discharge standard (gb8978-1996). comparing to the standard fenton oxidation, the application of fluidized-bed fenton reactor resulted in an improvement of over 13% on codcr removal efficiency, as well as a reduction of 70% on sludge yield. accordingly, the operating costs can be reduced by 28%, which could be controlled within 3.0 yuan/tons wastewater in stable conditions. key words： fluidized-bed fenton; advanced treatment; synthesis pharmaceutical wastewater  前言  医药化工废水是一类水质成分复杂、有机污染物浓度高、含有较高氯化物等无机盐、可生化性差的工业废水，特别是合成制药废水，大多含难降解有机物[1]。目前大多数合成制药企业的废水处理都采用传统的以生化为主体的处理工艺[2]，一方面废水污染物浓度高、对微生物系统高效运行影响因素多，处理效率低；另一方面随着环保要求日益提高，废水处理达标率逐渐下降,许多企业废水排放难以达标。因此，研究经济适用的合成制药废水深度处理新工艺势在必行。 流体化床fenton氧化工艺是非均相fenton氧化技术基础上发展而来的, 主要原理是将fenton氧化法产生的三价铁在流化床中的载体表面产生feooh的结