FACTSCa复合材料对酸性大红3R的吸附研究.doc

Ca/CTS/FA复合材料对酸性大红的吸附研究 韩双艳，李北罡* (内蒙古师范大学 化学与环境科学学院，内蒙古 呼和浩特 010022）fly ash，FA)为原料，通过负载壳聚糖和钙离子制备一种新型吸附剂(Ca/CTS/FA)用于酸性大红3R(Acid scarlet 3R，AS 3R)染料的吸附去除，考察了最佳吸附条件和吸附性能，探讨了吸附动力学、吸附热力学及复合吸附剂的再生。结果表明：水体pH、吸附时间和均对吸附有影响Ca/CTS/FA对AS 3R的吸附动力学均能用准二级吸附速率方程精确描述R2=1.00）Langmuir模型、Freundlich模型和Dubinin-Radushkevich(D-R)模型进行拟合，结果表明等温吸附行为更符合Langmuir模型；同时也较好地符合Freundlich模型和D-R模型，由D-R方程获得的平均吸附能、表观活化能及热力学研究均表明该吸附过程由化学吸附、物理吸附和氢键作用共同控制。热力学参数中吸附自由能变为负值、焓变为正值说明该吸附是吸热性质的自发过程。Ca/CTS/ FA复合吸附剂能用0.01 mol·L-1 NaOH溶液再生，至少可循环使用8次以上，再生率均在99%以上。 关键词：粉煤灰；壳聚糖；复合材料；酸性大红3R；吸附 中图分类号：X703 文献标识码：A文章编号：Adsorption of Acid Scarlet 3R by Ca/CTS/ FA Composite from Aqueous Solution HAN Shuang-yan , LI Bei-gang (The College of Chemical Environmental Science, Inner Mongolia Normal University, Hohhot 010022, China) Abstract: In order to improve the utilization of fly ash and enlarge the scope of its application in the field of wastewater, a new adsorbent, Ca/CTS/ FA composite prepared by loading chitosan and calcium ion onto fly ash was used for the removal of Acid scarlet 3R(AS 3R) from aqueous solution. The optimum adsorption conditions and adsorption properties were investigated. The adsorption kinetics and thermodynamics and the recycling of the composite adsorbent were discussed. The results show that solution pH, amount of adsorbent, contact time and oscillation frequency all affect the adsorption. The adsorption process can be accurately described by the pseudo-second-order kinetic equation（R2=1.00）.The isotherm data were analyzed using the Langmuir, Freundlich and Dubinin-Radushkevich (D-R) isotherm models, the results indicate that the adsorption behavior fitted better with the Langmuir model than others. The adsorption data is also in good agreement with Freundlich and D-R model, and the average adsorption energy obtained by D-R equation, the apparent activation energy and thermodynamic study show that the adsorption may be completed through chemisorption, physical adsorption and hydrogen bonding. Th