对Luminol－H2O2－CrⅢ体系的化学发光熄灭效应.docVIP

稀土Yb(Ⅲ)对Luminol－H2O2－Cr（Ⅲ)体系的 化学发光熄灭效应 研究了稀土Yb(Ⅲ) 对Luminol－H2O2－Cr(Ⅲ)体系化学发光的熄灭效应，在此基础上建立了稀土Yb的流动注射化学发光分析法。该法灵敏度高，线性范围宽，仪器设备简单，操作方便。关键词　稀土，镱，流动注射，化学发光分析，鲁米诺 Quenching of Rare Earth Yb (Ⅲ) Ion in the Chemiluminescence System of Luminol－H2O2－Cr(Ⅲ) Zhu Zhijia(Experimental Center，Hebei Normal University，Shijiazhuang 050016) Abstract A method of flow injection chemiluminescence analysis for the determination of rare earth Yb(Ⅲ)ion is presented. It is based on the quenching effect of Yb(Ⅲ) ion in the chemiluminescence system of Luminol－H2O2 －Cr(Ⅲ). The detection limit and linear range are 3×10－2 μmo