内循环流化床吸附-膜分离地下水除氟工艺中试研究.pdfVIP

中试装置出水的Al3+含量满足国家规定的0.2mg/L 的标准；通过对运行成本分析 可知，中试水平下，该工艺的动力费为0.52 元/ 吨，药剂费为0.9 元/ 吨。 建立了完全连续流运行方式下的水质预测模型，得到单位重量吸附剂产水能力只 有序批运行和连续-间歇式运行产水能力的43% ，从侧面说明中试连续-间歇式运行方 式的设置是合理的。 关键词：吸附，膜分离，流化床，活性氧化铝，除氟 II 万方数据 Abstract There commonly exist high-fluorine problems of groundwater in most areas in China to varying degrees and there are a great number of people drinking the high-fluorine water as yet. The present commonly-used fixed-bed defluorination technology has a lot of defects such as low utilization of adsorbent, frequent regeneration, easy caking of adsorbent, low degree of automation, hard to miniaturize, nontransparent cost of running, etc. Hence, developing a new defluorination technology, which is suitable for country areas, is being pressed for. Activated alumina was selected to process fluorine-containing groundwater via a pilot-scale integrated MAR (membrane adsorption reactor) apparatus designed by our research group. The reactor is an internal-circulating fluidized bed in which a set of microfiltration membrane module is imbedded to separate particles of alumina from water. Sequence batch mode and continuous-flow intermission mode were respectively choosed to experiment by programmable logic controller. The rate constant (k) of the pseudo-second order adsorption model was formulated - with activated alumina dose (a) and initial sorbate (F ) concentration (C ) by surface fitting 0