炼油厂含油废水处理工艺设计--毕业论文汇.docxVIP

摘要随着工业进程的深入，工业化发展迅速，石油化工行业也得到了迅猛的发展。同时也带了各种环境污染问题，炼油废水排放量大，油类物质浓度高，污染物成分复杂，直接排入自然水体或土壤对环境危害巨大，因此对炼油厂含有废水进行处理与回用是及其必要的。本设计中炼油厂含油废进水水质情况：pH：6-9、石油类：300-1200mg/L、CODCr：500mg/L、BOD5：400mg/L、SS：500mg/L、NH4-N：25mg/L、S2-：20mg/L。根据炼油厂含油废水的水量、水质特点分析、结合当地自然条件、排水标准要求等因素，进行工艺比较及一系列参数论证，确定的工艺流程为：含油废水→细格栅→集水池→隔油罐→油水分离器→调节池→一级涡凹气浮、二级溶气气浮→水解酸化→初沉池→A/O反应池→二沉池→臭氧消毒→出水。含油废水通过细格栅后进入集水池，经提升泵提升后进一次进入隔油池和油水分离器，去除大部分悬浮油，一级涡凹气浮和二级溶气气浮能去除废水中剩余的悬浮油和绝大部分分散油。水解酸化池能提高含油废水的可生化性，为后续的A/O工艺提供较为稳定的进水水质，A/O反应池由缺氧池和好氧池组成，具有良好的脱氨和降解有机物能力。经二沉池沉淀和臭氧消毒后出水。污泥经浓缩脱水后外运处置。方案预计的出水水质各项指标：pH：6-9、石油类≤3.0mg/L、CODCr≤50mg/L、BOD5≤10mg/L、SS≤50mg/L、NH4-N≤5mg/L、S2-≤0.5mg/L，达到《石油炼制工业污染物排放标准》（GB-31570-2015）中的水污染物排放要求。方案预期石油类去除率为99%以上，CODCr去除率为90%以上、BOD5去除率为97.5%以上、SS去除率为90%以上、NH4-N去除率为80%以上、S2-的去除率为97.5%以上。该工艺对炼油厂含油废水的处理具有良好的预期效果，与老工艺相比较具有明显得优点，运行稳定处理效果好，在炼油废水的处理具有广阔的应用前景。关键词： 含油废水； 隔油； A/O工艺 AbstractWith the deepening of the industrial process, industrialization has developed rapidly, and the petrochemical industry has also developed rapidly. At the same time with a variety of environmental pollution problems, refinery wastewater emissions, oily substances, high concentration, complex composition of pollutants, directly discharged into natural water or soil is very harmful for the environment, so the refinery containing wastewater treatment and reuse is necessary and.In this design, the water quality of oily waste water in refinery is: pH:6-9, petroleum: 300-1200mg/L, CODCr:500mg/L, BOD5:400mg/L, SS:500mg/L, NH4-N:25mg/L, S2-:20mg/L. According to the characteristics of water quality of oil refinery waste water, analysis, combined with the local natural conditions, drainage standards and other factors, the process and a series of parameter argumentation, determining the technological process: oily wastewater→sump→fine grid→isolation tank→oil-water separator→ regulation pool→level two, CAF dissolved air flotation, hydrolysis acidification→primary sedimentation tank→A/O reactor→two sedimentation tank→ozone disinfection. Oily