电化学法处理hns生产废水的实验及理论研究-环境工程专业论文.pdf.docxVIP

Fenton试剂，COD去除率达到74.67％，同时色度去除率为99.25％。若仅加入相同剂量Fenton试剂，不进行电化学处理HNS生产废水，完全反应后COD去除率未能测出，色度的去除效果也不理想，由此推断Fenton试剂协助促进了羟基自由基[·OH]的生成率和利用率。(4)电化学反应过程中生成大量中间产物，随着羟基自由基[·OH]等强氧化活性物质生成，小分子物质如直链有机酸被直接氧化生成水和二氧化碳，而大分子物质的降解历程可能是双键先断开，氧化降解成多硝基类化合物，逐步被还原为易于氧化的胺基类化合物，再在[·OH]羟基化作用下氧化降解。关键词：电化学，HNS生产废水，DSA电极，高级氧化技术TreatmentofHNSWastewaterbyElectrochemicalMethod AbstractHNSwastewaterinproduction,ishard-decomposedwastewaterinindustry,possesses featuresofbeingcomplicated,strongchroma,highpoisonous,largequantityof macromoleculewhichishardtobedecomposedandhighdensityoforganics.Asanew greentechnology,Electricchemistryemployedelectronasreagenttovalidatelossandgain reactioninwhichstrongoxidation,hydroxylradicalswithnosecondarypollutionor vigorouslyactivesubstances ofoxidationweregeneratedtodealwithwastewaterfilledwith highdensityandpoison.Inthisway,noextrachemicalreagentsareneeded,otherpoisonous substancescouldnothavemuchchancetoshowupintheprocessofdegradationanditis calledfriendlyenvironmenttechnologyforitsadvantageoflowcost,highefficiency,little pollutionandeasyoperation.Theresearchdesignofthree-dimensionalelectrodereactorwithatitaniumplateasa cathode,respectivelystudyRuO2-IrO2-TiO2/Ti,RuO2-IrO2-SnO2-TiO2/Ti,IrO2-Ta2O5-TiO2/Ti andIrO2-Ta2O5-SnO2-TiO2/TifourDSAanodematerialeffectofdegradationunderthe conditionsofdifferentvoltage,andthereactiontime,theelectrodespacing,pHvalue,over anhydrousNa2SO4dosage,wastewaterinitialconcentrationtoobtainthedegradationofthe optimalreactionconditions.Onthisbasis,alsostudiedtheproductionwastewaterdegradationeffectsonHNSaddto Fentonsreagent.WithDSAelectrodeonpositivepoleandpure titaniumnegative,conclusionwasdrawnfromstudyofdegradationofHNSwastewaterin productionbyanalyzingpotassiumdichromateandmethodofmultipledilutions asfollows:Homemadethree-dimensionalelectrodereactorprocessingHNSproduction wastewater,experimentalconditions:wastewaterinitialconcentrationof6240mg·L-1,voltage 8V,reactiontime4h,theelectrodespacing0.5cm,Na2SO4was0.375g·L-1,pH6,filler particl