异质掺杂改性二氧化钛及其光催化性能研究-化学工程专业论文.docx

ABSTRACT硼Dvidin2 e街cient，deaIl aIld regenerated resource and e衔ci饥t enViro咖ental胁ent．111 recent years，semiconductor photocatalytic materials exhibit an ideal way ofAs one kind of photocatalysts，Ti02 has been widely used for 11igh photocatalytic acti、，ity，thorou曲ly photode擎adation ofganics and chemicm st吞bility without secondary pollution． Howeverthere are some problems dlmng the practical dl锄ical industrial application and promotion of Ti02，owing to relatively wide baIld gap and n躺w range of photoresponsef九387胁)．In this dissenation，our main ideas are synthesizing，characterizing，andcalculatin2 me crystal s仃Ilcture aIld photocatalnic perf．o咖aIlce of Ti02-basedphotocatalvtic materials．The main points could be summarized as{-0110ws：Firstlvwe synmesized Ti02 bv hvdrothe蛐a1 svnmesis crystallization method a11dchal．act丽zed their phase structures， surf’ace property ttlrou曲T}ansmission ElectronMicroscopy (TEM)， Field Emission Sca皿ing Electron Microscopy (SEM)， X—raydi丘hction fXRD)，X．rav Photoelectron Spectroscopy(XPS)． Brookite aJld Anataseprepared as hYdrotheHllal time and temperature increasing f如m 1 h to 24 h aIld疗om 353．15 K to 453．15 k，respectivelv’and me cnrstallite size of s锄ples increased withhvdrothennal time and temperature．At me same time，based on homemade Ti02 and commercial Degussa P25，s锄ples prepared by impregnation and calcination method and charact耐zed bV SEM，TEM，XPS，UV-Ⅵs，R锄an，getting to know the crystallite size ofCuO aIld Fe203 is 5．1 O nm，element composition and valence state is Cu”，Fe十’，0’7，Ti”and discoVering Cu0，Fe203．The photocatalytic hvdrogen production and degradation of methyl orange(MO) experiments were perfomed to test samples photocatalvtic activitV and contraStiVe analyzed photocatalytic activity of degradation M0 reaction of s锄ples(2CT，2FT’2CFT’CT2，FT2， CFT2，CP2，FP2 and CFP2 prepal．ed bV the different preparation and modification memods)under ultravi01et，visible li面t irradiation．It is concluded mat both ultraviolet and visible li叠ht illum