支护锚杆表面化学镀层的制备与性能研究-材料工程专业论文.docxVIP

太原理工大学硕士研究生学位论文针对不同热处理温度的化学镀Ni-P合金镀层，为探讨热处理温度与镀 层耐蚀性能的关系，作者在分形理论的方法指导下对镀层进行分形维数分 析计算，尝试在分析和判断热处理温度与耐蚀性关系方面寻找一定的理论 依据。分形研究表明，Ni—P合金镀层表面具有分形特征，分形维数的变化 情况与镀层的耐蚀性能呈现一定的正相关关系。由于分形维数只是镀层表面的形貌结构和复杂程度的直观表征，因此通过分形维数变化情况分析镀 层的耐蚀性能具有一定可行性，可做一些定性判断。通过在镀液中添加稀土La的试验，综合分析了La元素的不同添加量 对镀层的组织结构、形貌、成分及耐磨耐蚀性能的影响。稀土镧对Ni-P镀 层的表面形貌有显著影响，起到细化和修饰晶粒作用，胞状组织更加致密， 镀层结构具有明显的微晶衍射特征。当添加量为0．25 g／L时镀层质量最佳， 在往复磨损试验中，磨损程度轻微，整体上呈现出良好的耐磨损性能，但 总体上看，稀土的添加对镀层耐磨损性能的影响作用不大。电化学极化曲 线和阻抗分析结果表明，镀层在La3+添加量为0．50 g／L浓度下，自腐蚀电 位最大，自腐蚀电流密度最小，溶液与基体之间的阻值最大，具有突出的 耐蚀性能。关键词：锚杆，化学镀Ni—P，热处理，分形，稀土，耐磨性，耐蚀性万方数据太原理工大学硕士研究生学位论文PREPARATIoN AND PROPERTIES oF ELECTROLESSPLATING COATING oN ANCHOR RODIN SUPPoRT ENGINEEIUNGAB STRACTThe underground support engineering is a concealed work．As vital support material，anchors play an important role in the construction and safety aspects． Anchors are generally applied in the laneway,mine，tunneling and rock slope engineering，in which they are prone to deteriorate under complex and adverse geological conditions，thus durability and service life of the anchor has been agreat threat．Wear and corrosion resistance of anchors has become the focus of research．In order to predict the mechanical behavior of anchor rod passing through the complicated areas under harsh environments and increasing the usage of anchor rod in bracing proj ect，electroless plating was conducted to form Ni-P coating on RB400 steel for improving the surface performance．The surface and cross—section morphology of the coating were measured by scanning electron microscope(SEM)and metallographic microscope，phase composition andIII万方数据太原理工大学硕士研究生学位论文sectional element distribution were determined by X—ray diffraction(XRD)and glow discharge optical emission spectrometry(GDOES)．A reciprocatory type tribometer and electrochemical workstation were applied to evaluate the wearand corrosion resistance of anchor rod steel and Ni—P coating，respectively．On the basis of dual Ni—P plating，through a combination of chemical plating after the hea