新型富镁基合金的制备及其储氢性能研究-材料物理与化学专业论文.docxVIP

AbstractIn this work, we focus on the preparation and hydrogen storage properties of Mg-rich Mg-Ni-La and Mg-Ni-La/Y-Co system alloys. Firstly, we research the effect of rapid solidification on phase structure and hydrogen storage properties of Mg60Ni30La10 alloy from the perspective of two preparation methods. Secondly, we study the effect of Co content on phase structure and hydrogen storage properties of Mg60Ni30La10-xCox (x=0, 2, 4) and Mg60Ni30Y10-xCox (x=2, 4) alloys by adding Cobalt. Finally, we research the effect of Re on phase structure and hydrogen storage properties of Mg90(ReNi3)10 (Re=La, Pr, Nd) alloys with high magnesium content.For Mg60Ni30La10 alloy, XRD patterns and SEM imagines show that the Mg60Ni30La10 alloy contains MgH2 and Mg2NiH4 phase after hydrogenation of 573 K and 2 MPa, while the rapid solidification alloy mainly contains La4H12.19 phase and the arc melting + mechanical alloying alloy contains La8H18.40 phase. From kinetic curves, it can clearly be seen that the rapid solidification alloy shows the maximum hydrogen absorption/desorption capacity. However, arc melting + mechanical alloying alloy has the maximum hydrogen absorption/desorption rate. The dehydrogenation activation energies of Mg60Ni30La10 alloy are calculated by Kissinger method, showing the values of 99.94±5.15 101.68±8.97 kJ/mol for the rapid solidification alloy and the arc melting + mechanical alloying alloy.For Mg60Ni30La10-xCox (x=0, 2, 4) alloy, after hydrogenation of 573 K under 2 MPa hydrogen pressure, XRD pattern results indicate the formation of new phases of MgH2 (x=0, 2, 4), Mg2NiH4 (x=0, 2, 4), La4H12.19 (x=0, 2, 4), Mg2Ni0.9Co0.1H4 (x=2), Mg2NiH0.26(x=4), Mg2CoH5 (x=4). It is observed that the experimental data of hydrogen desorption kinetics at 523 K, 553 K, 573 K are well fitted with Avrami-Erofeev equation. Based on the results of Kissinger analysis, dehydrogenation activation energies of these alloys aredetermined to be 91.38 ±2.82 kJ/mol (