新型多孔碳纳米材料的制备及其电化学应用-药物分析学专业论文.docx

ABSTRACTPorouscarbonnanomaterials，becauseoftheirlargersurfacearea，regulatedporestructure，highelectronicconductivity，andexcellentchemicalstability，haveattractedmoreandmoreattentionintheapplicationsofsupercapacitorsandelectrochmicalsensing．Theperforamceofsupercapacitorsandelectrochemicalsensorsarestronglydependentontheusedelectrodematerials，SOthepreparationofnovelporouscarbonmaterialsfromnewcarbonprecursorsusingnewsyntheticmethodsandexploitingtheirapplicationinsupercapacitorsandelectrochemicalsensingareofgreatimportance．．Inthisthesis，severalporouscarbonnanomaterialswerefacilelysynthesizedwithdifferentprecursorsusingdifferentsyntheticmethods，andtheseporouscarbonnanomaterialsweresuccessfullyusedforsupercapacitorsandelectrochemicaldeteriminationofsmallbiomolecules．Themaincontentsareasfollows．1．AnewporouscarbonwaspreparedusingricehuskasacarbonprecursorbythedirectcarbonizationandsimultaneousKOH—activation of．Theas—preparedporouscarbonservedasanelectrodematerialforsupercapacitors showedhighspecific capacitance，excellentratecapability,andgoodcyclingstability．2．Three-dimensionalactivatedgraphenenetworks(3DAGNs)wereIII万方数据synthesizedbythedirectcarbonizationandsimultaneouschemicalactivationofacobaltion-impregnatedD113一typeionexchangeresin．Then，a3DAGNs-sulfonate．terminatedpolymer(STP)nanocompositewas prepared via the in situ chemical CO—polymerization ofm．．aminobenzenesulfonicacidandanilineinthepresenceof3DAGNs．The3DAGNs-STPnanocompositemodifiedglassycarbonelectrode(GCE)wasusedfortheelectrochemicaldetectionofdopamineinthepresenceofascorbicacidanduricacid，withabroadlinearresponserange，highsensitivity,andlowdetectionlimit．3．DirectpyrolysisofamixturecomprisingpolyanilinenanofibersandironnitrateisfoundtobeanasimpleandscalableapproachtothesynthesisofFeandNCO—dopedgraphenenetworksforoxygenreductionreactioninacidicsolutionswithhighcatalyticactivityandexcellentdurability．ThegraphenemodifiedGCEwassuccessfully usedforsimultaneousdetectionofascorbicacid，dopamineanduricacid．Keywords：PorousC