聚氨酯%2fposs纳米纤维膜的制备及血液相容性研究.pdf

ABSlRACT WaS thereactionofToluene and Polyurethane synthesizedby 2，4-diisocyanate poly aclassofblock with unitof tetrahydrofuran(PTMG)ascopolymerrepeat and themolecularofthe was methane，then polyetherpolyols weight polymer increased chainextender hard is byadding 1,4-butanediol(BDO)．Thesegment and of chain thesoft is a composed extender,and isocyanate segmentsusuallypoly01． and 2％POSS-PUwere theadditionof PU，1％POSS-PU synthesized 0wt％， by 1 POSS the wt％and wt％，2wt％TriSilanollsobutylrespectively．We0wt％，1 prepared 2wt％POSS-PU nanofibers of eleetrospinningbyelectrospinningtechnique．Analysis thefiber was studied electron obtainedthe morphology byscanning microscopy,we of conditions：ConcentrationPOSS-PUis12％．the optimumspinning spinning is20 distanceis20 extrusionis0．8mL／h．The voltagelcv,receiving cm，the speed contactoflwt％and2wt％POSS-PU fibersmembraneincreased12．50 electrospun and24．3。．Theresultsof testsshowedthatthePOSS-PU