直接甲醇燃料电池阳极微细通道内气液两相流的研究-化学工程专业论文.docx

研究表明：在通道中具有泡状流、弹状流、环状流以及他们的混合流等流动形态，没有发现分层流和波状流等流动形态；增大液速可以减少通道内弹状流和环状流出现的区域面积；通道的尺寸对通道内流型具有一定的影响；最后通过气体的质量流量分数和气体表观速度得到了固定液速下的流型图。本文的研究结果对合理的选择DMFC操作条件，提高阳极通道内的传质效率和燃料电池的输出功率具有一定的指导意义。关键词：DMFC，气液两相流，微小通道，数值模拟，气体表观速度，液体表观速度，流型图RESEARCHONGAS-·LIQUIDTWO·-PHASEFLOWINANODECHANNELOFDIRECTMTHANoLFUELCELLABSTRACTTheanodechannelofdirectmethanolfuelcell(DMFC)isusedtotransportthereactantsandproducts，whichensurethattheeachplaceofanodecanobtainSUfficientmethan01andthecarbon．dioxidecanberemovedimmediately．Whenthecarbon—dioxideproducedinthesurfaceofcatalystlayerpassesthroughthegas diffusionlayer(GDL)andenterstheanodechannelwithmethanolsolution，thegas—liquidtwo—phaseflowwhichhasasignificantimpactontheperformanceofbatterybeginstoform．ItwillproducemorecarbondioxideasthecurrentdensityincreasesandbedifficulttodischargetheDMFCatthesametime．Theanodechanneliseasytojam．Inaddition，thegasfilmformedinthesurfaceoftheGDLdoesnotfavorthemethanoltransportationtothesurfaceoftheanode．Therefore，itissignificanttostudythegas—liquidtwophaseflowintheanodechannelofDMFC．Inthispaper,thetwo—phaseflowinananodechannelofDMFCwassimulatedbycommercialsoftwareFluenttostudytheeffectsofhydrophilic／hydrophobicpropertiesongas·-liquidtwo--phaseflow．TheresultsshowedthatcarbondioxidedischargedquicklyoutoftheanodechannelanditwasdifficultforthereactantstotransporttotheGDLwhenthesidewalloftheanodechannelwasfilledwithhydrophobicandittookmoretimeforcarbondioxidetomoveoutoftheanodechannelinananode channelwithhydrophilicchannelside-wallandhydrophilicGDLsurface．Theanodechannelwithhydrophilicchannelside—wallandhydrophobicGDLsurfacefacilitatedthegasdischargingoutoftheanodechannelandliquidtransportingtoGDL．Avisiblesmallchannelof2mmx2mmx149mmwasemployedtosimulatetheanodechannelofDMFCandtostudythegas—liquid two—phaseflowunderdifferentconditions．Theresultsshowedthatbubblyflowregime，slugflowregime，annularflowregimeandthehybridsoftheseflowregimeswhichencounteredinconventionallargechannelswerefoundinthisvisiblesmallchannel．However,thestr