金属钴粉化学镀铜复合材料的制备、表征及催化环己烯氧化性能研究-化学工程与技术专业论文.docx

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2018-05-05 发布于上海
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金属钴粉化学镀铜复合材料的制备、表征及催化环己烯氧化性能研究-化学工程与技术专业论文.docx

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金属钴粉化学镀铜复合材料的制备、表征及催化环己烯氧化性能研究-化学工程与技术专业论文

AbstractThestudyofcatalyticcyclohexeneoxidationgraduallyhasbeenpaidattentioninacademiaandindustryfiled,itsoxidationproductshaveawiderangeofapplicationsinthepetroleumchemicalindustry,finechemicalandpolymermaterialsandotherfields.CyclohexenemoleculehasasusceptibleoxidationC=Cbondandapluralityof α-Hatom,ifoxidationreactionoccursontheC=Cbond,oxidationproductsarecyclohexanoldiol,epoxycyclohexane,aldehydeandcarboxylicacid.If oxidationreactionoccursontheα-Hatom,couldgenerate2-cyclohexene-1-alcohol,1-2-cyclohexene-ketoneorcyclohexenebaseperoxideandotherhighvalue-addeddown-streamproducts.Atpresent,thestudyofcatalyticoxidationofcyclohexenemainlyusingsolidacid,organicmetalcomplexesandorganicmetalsaltsasthecatalyst,althoughtheconversionandselectivityareimprovedgreatly,butmost ofthereactionneedtousetheorganic solventorphasetransferagent, andmostofthe reactionusehydrogenperoxideandtert-butylhydrogenperoxideandhydrogenperoxideasoxidant,thereissignificantlyhighercostandenvironmentpollutionproblems.Inthissubject,Co/Cu-ELD,Ti/Cu-ELD，C/Cu-ELDandAl/Cu-ELDcompositecatalystswerepreparedbyelectrolesscopperplatingmethod,undersolvent-freeconditionsandmolecularoxygenasanoxidant,thecatalyticpropertiesof cyclohexeneoxidationreactionwasstudied.Themaininnovationpointisthatcompositematerialsofmetalcobaltpowder/electrolesscopperplatingwerepreparedforthefirsttime,anddiscussestherelationshipbetweenitsstructureandtheperformanceofthecatalyticoxidationofcyclohexene.Themainresearchworkisas follows:Usemetalcobaltpowderassubstrate,sodiumhypophosphiteasthereducingagent,usingthemethodofelectrolesscopperplatingprepareddifferent Cu/Comolratioofcompositecatalyst,itscompositionandstructurewasstudiedbyICP, XRD,BETandSEM.Undersolvent-freeconditions,oxygenasoxidant,thecatalyticactivityofCo/Cu-ELDforcyclohexeneoxidation reaction wasstudied,ForCo/Cu-ELD-5catalyst,ithasbettercatalyticactivity,UsingTEMandXPScharacterizationthecompositionandproperties,andinvestigatestheeffectofparameterssuchasreactiontemperature,reacti