特殊形貌氧化锆的控制合成及发光性质初探-无机化学专业论文.docx

AbstractV撕ousnoVelprop硎esofZr02n趾os仇lcturesst锄丘Dmtllechemicalcornponent，equallyimportaIlt，matnleseprop硎eschangewim陀speCtt0specificsize，mo印hologyandsup枷ctufe．B勰cdonthe缸efeStinpe谢iafshapedZ蛾i11di蚴applied6elds，m也ep他s姐tworkwehopet0C0ntrolmemlcleationandgrowmofiIlorg锄iccrystals讥aasimpleandmilds01ution—growthm如od．N0mlallow-moleculaf-weightmicfom01e∞lar0rgamcadditiv懿，跚晌ctantt锄叩1et砒ld the皿croreactionpool，锄d枷丘cialactiV砷edmJcleationpointSha、rebeenshowntoexertsi嘶ficantmofph010百calinfluenceonmecrystallizationof瑚n0-盈02．1Kswod(figuredoutandanalysedt11emodali妙ofmenano-zi瑚Ilia锄dpriIllarilydisc哪stheshapemechaIli锄．№锄ore，spec仃ala11alysisofmepeCuli缸Zr02h觞beeninVestigated．Tbemaillcont钮tsareshownasbelow：1．Reviewedmepr0莎锶sofShap争colltrollednaIlomaterials，emph纽sodonthree咖esofspecialmodal姆zir∞llias)rflmeticalmemodsandanalysisedmeirch甜被面stics；2．NanorodandNaIloclust盯Zr02weresynⅡlesizedint11epresentinVestig撕onviac0蜘petitionofcoⅡlplexation孤ldd印ositionofzircon妒cldoride，sodi啪hydroxideandmicromoleclllet锄plat韶in锄alcollolS0lution．Then赳10．stlllctural盈02haVeteh．agonalorcubicnucl蒯onini矗at0巧ph硒esr唧ectivelyWitllmem玳asingcalcin撕ont锄peratI鹏，nleShap骼ofzr02眦eun柏爸cted，w蛐eultimate妇nsf0胁ationt0monodinjcph雒eis3．Aquat锄哪“water-in—oil’’microemulSionofhex锄e(hyl铋ealkyl舔oil，pentanol粥me弱su】晌ct锄t’V耐ouSb，pesofsllrf；蟛tant，andtheiIl唧ensiveZ幻C12‘8H20aSzircolliumfountain，sodiumbic抽onate勰meprecipitatorw弱usedt0pr印aret11etllbe，blossom，cypress，曲bon—liken锄。一zirconia．111eabno彻alonllorhombicphaSezr02c锄bedetected．Itmightbea晒butedto也enano—sizeofori百nalp枷cles；4．Ontllebasisofw／0microemulsionand伊aVityselfassemblyteclulolo鼢ordered—structureSnaIlo—zr02withblock，ballorinterimsh印esaredepositedon西assbase．The西asesubstrateViathreeprocessingtookonspecialsurfacec_haracters，whichproVideddif]衙efltnuclearactivitypoints．Thusnano-Z内2ordered—structureswithdiVersifiedshapesself二aSseInbled：5．PLspectmmobtained6．omShape-controlledZr02nanostmctures．Theemissionpeaksexhibitamaximumat468m，ashoulderabout484眦，whenthes锄plewasexcitedwitllli曲tof425nmwaVelengths，in