染料敏化太阳能电池材料的设计合成与性能研究-应用化学专业论文.docx

AbstractDye-sensitized solar cells (DSSC) based on organic dyes have become more and more popular and represented the future development direction of the dyes because of their high photoelectric conversion efficiency and low cost. At present, the organic dyes usually contained a donor group (such as: with N, O functional groups), a spacer and an acceptor group (such as: CN with the required COOH) to form donor-π-acceptor structure. In this paper, brief introduction of dye-sensitized solar cell’s theory, structure, status and development trend were outlined. And we have designed and synthesized twelve new dyes. The structures of the dyes have been proved and confirmed by 1HNMR and 13CNMR. The photophysical, electrochemical and photovoltaic properties of the dyes have been studied by UV-vis absorption spectra, photoluminescence spectra and cyclic voltammograms. The main contents are listed as follows:First, six new organic dyes contained tetraphenylsilyl as electron donor and cyanoacrylic acid or rhodanine-3-acetic acid as electron acceptor bridged by thiophene units were designed and synthesized. The maximum absorption peaks of dyes TPS1, TPS2, TPS3, TPS4, TPS5, TPS6 are located at 439 nm, 472 nm, 449 nm, 482 nm, 452 nm, 484 nm, respectively. They have showed broad absorption band, and the absorption spectra have covered with visible spectra. From the results of electrochemical cyclic voltammetry, these six dyes bandgaps are almost agreed well with optical bandgaps. Along with increase the number of thiophenes, absorption band have broader.Second, we synthesized and charactered the other six novel dyes. They have triphenylamine(TPA)-based as electron donor and cyanoacrylic acid or rhodanine-3-acetic acid as electron acceptor and bridged by benzo[1,2-b:4,5-b’] dithiophene, bithieno[3,2-b:2’,3’-e]pyridine and bithieno[3,2-b:2’,3’-e]pyrrole units. The maximum absorption peaks of dyes TPD1, TPD2, TPD3, TPD4, TPD5, TPD6 are located at 430 nm, 464 nm, 470 nm, 513 n