气体二氧化氯的光解规律分析-环境工程专业论文.docxVIP

The Research on Photodecomposition Rules of Chlorine Dioxide GasAbstractIn recent years, the chlorine dioxide gas has attracted more and more attention because of its safety, broad spectrum, and easy to spread in sterilization, disinfection and food preservation. However, the characteristic of easy to decomposition in light, bring a barrier for its application and promotion. For the above reasons, the study on decomposition rules, influence factors, the structure of chlorine oxide and decomposition mechanism of chlorine dioxide gas was carried out. As follows:The study on the decomposition rate of chlorine dioxide gas and its influence factors Chlorine dioxide gas collection and photodecomposition experiment device isself-designed.the study on the decomposition rate of chlorine dioxide gas in different light sources, different temperatures and different initial concentrations, has been done. The degradation rate of Chlorine dioxide gas from fast to slow is the 354nm UV light, natural light, 257nm UV, fluorescence, and the dark room, indicating that the light making a key role on the photodecomposition rate of gradation of Chlorine dioxide gas is the wavelength of UV near the visible and the shorter wavelength of visible light; the concentration of Chlorine dioxidegas was not changed in darkness. In the range of 15 ~ 25 ℃, the temperature had no effect onthe degradation rate of the Chlorine dioxide gas.Chlorine dioxide gas in the high concentration (100 ~ 200mg / L), the time that the concentration of chlorine dioxide gas is half of the initial concentration is between the 50 ~60min; when the concentration was low (≤20mg / L), only 10 ~ 20min is used to completelydecomposition totally.The study on the structure and bonds of chlorine oxideBased on B3LYP/6-311 + G (3df) basis set, the structure, bond, angels, energy andvibration frequency was calculated. The results show that: the chemical bond which links the two momo-chlorine fragments of a di-chlorin