壳聚糖基纳米微粒的制备及其对ni2+吸附性能研究-应用化学专业论文.docxVIP

mg/mL时均可生成O-CMHACC纳米粒。粒度分析表明粒径主要分布在400～900nm。O-CMHACC纳米粒吸附Ni2+的最适pH为8，此时吸附容量最大且经1h就 达到吸附平衡。粒径较小的O-CMHACC纳米粒与金属离子的配位作用点更多， 从而吸附容量更大。对其进行了XRD表征和分析。使用HCl，脱附时间只需15min 便能达到90%以上的脱附率。四种脱附剂的脱附能力为HCl＞H2SO4＞HNO3＞ EDTA。4.在质量相同、粒径相同、取代度近似的条件下，对比三种纳米吸附剂对 Ni2+的吸附性能发现：O-CMCS纳米粒吸附性能明显优于HCS纳米粒，而二次 改性后的产物O-CMHACC纳米粒对Ni2+的吸附性能只较O-CMCS纳米粒略有 提高，不过耐酸性却得到了明显提高。关键词：改性壳聚糖，纳米微粒，吸附性能，Ni2+，离子凝胶法AbstractThewastewatercontainingheavy-metalionNi2+isgreatharmbothtohumanand environment,whichismainlyfromtheminingindustry,ferrousmetallurgy,metal processing,plating,instrumentationandvariousapplicationsofnickelcompounds business.Thus,theionremovedfromthewastewaterhasbecomeafocus ofconcern. Chitosanasanadsorbentofheavy-metalionsinindustrialwastewatercan’tengender pollutionagainandtheresourcesarereclaimedtoo,sotheresearchonchitosanhas importantsignificancebothinentironmentprotectionandthedevelopmentofcountry economy.However,itdoesnotgiveahighefficiencyandissolubleinacidsolutions. Moreover,theadsorptioncapabilityofmodifiedchitosanisnothighenough.Allof theserestricttheapplicationsofchitosan.Therefore,theideaofthispaperwas obtainedfromtheresearchhotspotofnano-materialsontodayscutting-edgescience. Modifiedchitosannanoparticles,which retainedcertain superiorperformancesof modified chitosan,werepreparedby ion gel in ordertoenhancetheadsorption capacityandincreasesomepropertiesofnano-materials.Theresearchindicatedthat nano-chitosan-basedadsorbentshadaveryhighadsorptioncapacity,andnano- adsorbentscanshowmanyfinefeatures.Themajorcontentsandresultswereas follows.Whenhydroxypropylchitosan(HCS)solutionconcentrationwas0.8~2.0mg/mL andsodiumtripolyphosphate(TPP)concentrationwasintherangeof0.4~1.0 mg/mL,HCSnanoparticlecanbegenerated.Theanalysisresultsofparticlesize showedthatnanoparticlesizemainlydistributedinthe200~300nm.TEM observationshowedthatthenanoparticlewasspherical.Theadsorptiveoptimum pHwas6.0~7.0,owningthegreatestadsorptioncapacityandrequiringonly1hto reachadsorptionequilibrium.Thesmallernanoparticleshadagre