毕业设计（论文）-高级脂肪醇碳酸月桂酯的合成研究汇.docVIP

高级脂肪醇碳酸月桂酯的合成研究 摘 要 润滑油的发展与国民经济的发展是密不可分的。随着我国车辆及机械设备的长足发展，润滑油也得到了快速发展。其中作为酯类润滑油，碳酸月桂酯是一种外观清澈的无色油状液体，它是一种性能优良的润滑剂基础油，具有良好的润滑性、不易结焦、积炭少和后处理简单的特点。 本实验，考察了、、时间、加热温度和对产品的影响，并采用对产品进行初步，得出最佳合成条件：，温度10℃，时间为h，。 关键字：esearch on synthesis of higher fatty alcohol lauryl carbonate Abstract The development of oil and the development of national economy is inseparable. With the rapid development of Chinas vehicles and machinery, lubricating oil also get a rapid development. As a kind of ester lubricant, didodecyl carbonate is a clear colorless oily liquid,it is a kind of good performance of lubricant oil, which has the characteristics about good lubricity, non-coke, little carbon deposit and simple post-treatment. The experimental explores the transesterification reaction of dimethyl carbonate and dodecanol(also called lauryl alcohol),and researchs the effect to product yield of different catalyst,the catalyst抲se levelr, the reaction time, reaction temperature and the ratio of the reatants, and uses gas chromatography for the quantitative analysis of products, and uses the preliminary to determine the dynamic viscosity of product. Finally concluded that the best synthetic condition of didodecyl carbonate: use trioxide iron/clay as catalyst in the the transesterification reaction of dimethyl carbonate and dodecanol;the mole ratio of dimethyl carbonate and lauryl alcohol is 1 to 3, heating temperature is 130℃, reaction time is 2h, catalyst’use level is 5% (mass fraction). The dynamic viscosity of product is 2.200mm2/s in temperature of 100℃,and 8.606 mm2/s in temperature of 40℃, was viscosity index is 37.04. Key words: didodecyl carbonate, dimethyl carbonate, dodecanol ,transesterification 目 录 1.前言 1 1.1合成润滑油 1 1.1.1合成润滑油的发展背景及现状 1 1.1.2合成润滑油的使用性能和要求 4 1.2酯类合成润滑油 5 1.2.1酯类合成润滑油发展现况 5 1.2.2酯类合成润滑油的分类及特点 6 1.3碳酸二甲酯 6 1.3.1碳酸二甲酯及其下游产品 6 1.3.2碳酸二甲酯酯交换反应 8 1.4本课题研究的目的与意义 9 2.实验部分 11 2.1 实验原理 11 2.2 实验原料与试剂 12 2.3 实验仪器 12 2.4 实验步骤 13 2.4.1催化剂制备 13 2.4.2合成反应与产物提纯 14 2.5产品分析 15 2.5.1气相