用于电动车 混合动力车的锂离子电池.pdfVIP

Lithium ion batteries for EV/HEV Jun-Kui Gao Tianjin Lishen Battery Joint-Stock CO., LTD. CLTF2009 May 23-24, 2009, Shenzhen Convention Exhibition Center, Shenzhen, China Outline 1. Challenges with Li-ion batteries for EV/HEV 2. Cathode materials 3. Anode materials 4. Lishen Li-ion batteries for EV/HEV 5. Summary Battery Depend on the Vehicle Type Higher battery energy content is typically achieved both by an increase in battery voltage and capacity ; From HEV to PHEV to EV, battery size and depth of discharge increase while rate requirements decrease; Comparison of present-day Li-ion batteries vs. EV/HEV goals(863) EV HEV Short point for EV and HEV: Calendar life, cycle life, operating Temp. range, power and energy density ,cost; Of course battery safety is first position. Technology challenges Safety: Large cells (for EV/HEV) have lower surface area to volume ratios and hence heat dissipation is more problematic than 18650 or other smaller size. Safety problems, therefore, for large cells are more serious. Operating temperature: Batteries for EV/HEV need to meet a wide temperature range of 60 ℃ to -25 ℃, especially at high temperature. Cycle/Calendar life: Batteries for EV/HEV need to cycle upwards of 3000 time. Also have to last 10-15years. Cathode materials used to EV/HEV batteries Comparison of Electrochemical Platforms (Cathode: as indicated Anode: MCMB Electrolyte: LiPF6 in EC:PC:EMC) Voltag Capacity Item Cycle Life Cost Safety e /V /(mAh/g) LiMn O 2 4 3.0-4.2 100～120 Low Low