基于贵金属纳米粒子的电化学传感器分析-化学专业论文.docxVIP

ABSTRACTWith the social progress of science and technology, people’s pursuit of life quality is getting higher and higher. At the same time, various environmental pollution problems are increasingly serious with the economic development. Aldehydes is a kind of carcinogenic and deformity caused by the highly toxic material, and threat to human health seriously. So it’s very meaningful to establish fast and accurate analysis of aldehyde detection method. As a new kind of detection tool, electrochemical sensors have advantages of high selectivity and sensitivity, and simple preparation, easy to implement online monitoring and rapid detection. Electrochemical sensors are widely used in various fields, such as biomedical, clinical diagnostics and environmental monitoring, and other fields. Nanometer sized materials, which have effects of macroscopic quantum tunnel effect, surface effect, quantum confinement effect and small size effect, are different from common sized materials on magnetic, electrical, thermal, optical, mechanical properties. The intervention of nanotechnology provides rich changes for the development of electrochemical sensors.In this paper, the electrodes modified with noble metal nanometer sized materials, which prepared by electrodeposition of noble metal salt mixture, were constructed. Their structure and properties were investigated with electron microscopy and electrochemical characterization methods. The main contents of this paper have been described as follows:① Construction and research of formaldehyde electrochemical sensor baseon nano Platinum-L-alanineNano Platinum modified GCE was constructed by cyclic voltammetry electrochemical method. The electrocatalytic oxidation of formaldehyde with L-alanine in the interface of the electrode was studied. The result showed that the electrochemical signal response of formaldehyde on the sensor was obvious. The oxidative peak currentof formaldehyde is linear to the concentration ranging from 2.00×10-5