活性自由基聚合,TEMPO2.pptVIP

2,2,4,4-四甲基派啶氮氧稳定自由基(2,2,4,4-tetramethyl-1-piperidinyloxy, TEMPO) Typically these propagating carbon centered radicals are transient species , tend to disappear by self-termination, which is typically a diffusion controlled process. This raises the question, why do we only see minor amounts of irreversible termination in NMP? 2.4 副反应 苯乙烯中的热引发： 说明双基终止的存在? 热引发对苯乙烯的聚合十分有利！ 双基终止的程度：严重影响速率，对分子量和分布影响很小！ 因自由基浓度:约为10-8M，大分子浓度为10-2M! 2.4 副反应 烷氧胺的分解或提氢副反应： 2.4 副反应 烷氧胺的分解或提氢副反应： These results help to explain the differences in the polymerization of styrenics and methacrylates under the same NMP conditi