钛酸锶热传导的研究.pdfVIP

Material Sciences 材料科学, 2014, 4, 73-79 Published Online May 2014 in Hans. /journal/ms /10.12677/ms.2014.43012 Thermal Conductivity Studies of SrTiO3 Ning Li, Huiqiong Wang, Yufeng Zhang, Zheng Huang, Fei Ren, Jincheng Zheng* Department of Physics, Xiamen University, Xiamen * Email: jczheng@ st th th Received: Apr. 1 , 2014; revised: Apr. 29 , 2014; accepted: May 7 , 2014 Copyright © 2014 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract In order to study the influence of oxygen vacancies in SrTiO3 on its thermal conductivity, SrTiO3 single crystals were annealed in high temperature under vacuum. The thermal conductivities of the as-received and annealed samples were determined by measuring their specific heat Cp of the samples using Differential Scanning Calorimetry (DSC) and their thermal diffusivities using Laser Flash Apparatus (LFA). The analysis showed that oxygen vacancies were generated during an- nealing which led to lower thermal conductivity, and the thermal conductivity properties of SrTiO3 conformed to the Debye model. Keywords SrTiO , Oxygen Vacancies, Thermal Conductivity, Debye Model 3 钛酸锶的热传导研究 李 宁，王惠琼，张宇锋，黄 政，任 飞，郑金成* 厦门大学物理系，厦门 * Email: jczheng@ 收稿日期：2014年4月1 日；修回日期：2014年4月29 日；录用日期：2014年5月7 日 摘 要 为了研究氧缺陷对钛酸锶热传导过程的影响，利用高温高真空条件下对钛酸锶进行退火，用高温型差示 *通讯作者。 73 钛酸锶的热传导研究 扫描量热仪测出单晶钛酸锶退火前后钛酸锶的比热，利用激光导热仪测出它们的热扩散系数，计算出它 们的热导率，比较它们之间的差异。之后结合德拜模型分析退火前后出现差异及比热和热导随温度变化 的原因。通过理论分析和实验相结合，得知钛酸锶在退火后产生氧缺陷，有效地降低了钛酸锶的热导， 并进一步验证了钛酸锶的热导性质