典型钢铁企业汞排放水平及排放特征研究.docVIP

典型钢铁企业汞排放水平及排放特征研究 宋祖华1高蓓蕾2 张迪生1 马光军1谢馨1武中林1 （1.南京市环境监测中心站 南京 210013 2.江苏省环境监测中心 南京 210000） 摘要：以某典型钢铁企业为研究对象，选择适用的测试方法，实际测试了企业废气、废水、固废汞排放水平，分析汞排放特征。球团、烧结、高炉工艺废气排口烟尘中汞排放浓度排放速率明显低于烟气，汞排放主要以气态形式排放。烧结工艺三个排口废气汞排放浓度相差较大，最高浓度排口废气汞排放浓度达719.48μg.m-3，分别是其他两个排口的7倍和3倍，主要原因是三个排口前端废气脱硫工艺的不同。球团、烧结、高炉、电炉四工艺环节中，烧结汞排放速率比重最大，占四工艺汞排放速率总和的87%。不同脱硫工艺对废气中汞的去除效率不同，半干法脱硫工艺对废气中汞的去除效率近90%，氨法脱硫对废气中汞的去除效率为78.7%，石灰石石膏脱硫工艺对废气中汞的去除效率仅有29.9%。企业废水排放未检出汞。脱硫产生固废汞含量明显高于除尘产生固废汞含量，脱硫灰汞含量是脱硫石膏的15倍。 关键词：汞 钢铁企业 排放 Mercury Emission Level and Emission Characteristics of the Typical Iron and Steel Enterprise SONG Zu-hua1, GAO Beilei2 ZHANG Disheng1,MA Guangjun1, XIE Xin1,WU Zhonglin1 (, Nanjing, Jiangsu 210013, China；2., Jiangsu Environment Monitoring Center Nanjing, Jiangsu 210000，China) Abstract：Taking a typical iron and steel enterprise as the research object, suitable test method, actual testing of the corporate waste gas, waste water, solid waste emissions of mercury level, analysis of mercury emission characteristics. The concentration of mercury in the flue gas exhaust smoke of the pellet, sintering and blast furnace process is obviously lower than that of the flue gas. Sintering process three row of the mouth of the mercury waste gas emission concentration difference is bigger, the highest concentration of row mouth of the mercury waste gas emission concentration of 719.48 mg.m-3, respectively, the other two row of mouth 7 times and 3 times, the main reason is three different outlet at the front end of the flue gas desulfurization process. In the four process of pellets, sintering, blast furnace and electric furnace, the proportion of the total mercury emission rate is the largest, accounting for 87% of the total mercury emission rate of the four process. Different desulfurization process of mercury in flue gas removal efficiency, semi dry desulfurization process of mercury in flue gas removal efficiency of nearly 90%, ammonia desulfurization of mercury in flue gas removal rate was 78.7%, limeston