atrp法制备两亲共聚物网络的分析word格式论文.docxVIP

（1）以三乙醇胺和2-溴异丁酰溴反应成功制备出星型ATRP引发剂；通过硅氢化反应将端氢硅油和乙二醇单烯丙基醚反应制备出大分子量的羟基硅油。通过羟基硅油和2-溴异丁酰溴反应制备出ATRP 大分子引发剂Br-PDMS-Br。(2)采用PDMS基大分子引发剂经ATRP制备出两亲嵌段聚合物PDMAAm-b-PDMS-b-PDMAAm，并对其端基溴进行了改性形成烯丙基。研究了不同改性剂、催化剂种类、反应时间、反应温度、反应物料配比等对改性效果的影响。将端基修饰过的两亲嵌段聚合物PDM AAm-b-PDMS-b-PDMAAm与交联剂反应生成APCN。此外，通过ATRP制备出了两亲嵌段聚合物PHEMA-b-PDMS-b-PHEMA为将来制备APCN提供了预聚体。(3)用合成的星型引发剂经ATRP成功的制备出了星型PDMAA m、星型PHEMA,讨论了反应温度、催化剂、反应时间、反应物料比对ATRP聚合的影响，并分别对星型聚合物端基进行了修饰，研究发现对星型PHEMA只能利用其端基的活性进一步引发单体甲基丙烯酸稀丙酯（AMA）聚合，然后可与交联剂反应形成APCN。研究发现单体HEMA相对于单体DMAA较活泼易进行ATRP聚合，较短时间达到较高转化率。APCN溶胀性能研究表明HEMA亲水性不及DMAAm。关键词原子转移自由基聚合，两亲共聚物网络，星型聚合物IITheStudy OnTheSynthesis OfAmphiliphicCopolymer Conectworks ByATRPABSTRACTAmphiphilic polymer networks(APCNs)isakindof polymernetwork systemconnectingby hydrophilic segmentsandhydrophobicsegments throughcovalentbonds,inwhichthephysical andchemicalnature ofhydrophilic segmentsandhydrophobicsegmentscouldberemained, respectively.Andthetwokindsofsegmentscanstillbeswellinginwaterandorganicsolvents, andtheyaggregatedtoformmicrophaseseparation.Becauseofitsunique properties,APCNs havegotwideapplicationprospectsinthefieldsofintelligentpolymermaterials,softcorneal contactlens, medicalmaterials andseparation materialsetc.Inrecentyears,atomtransferradical polymerization (ATRP)hasbeenthehottestresearchinpreparationofhighpolymers.Through thismethod,wecanobtainsize controllablepolymerswitharelativelynarrowmolecularweight distributionwhich canbe preparedasAPCNprepolymer, whichissignificanttoimprovethesize uniformityand propertiesof resltingAPCNs.Inthis paper, the PDMS basedmacroinitiatorand startype initiatorare synthesized to initiate theATRPofamphiphilicblockcopolymersandstarhomepolymers.Twokindsofmonomers, 2-hydroxyethylmethacrylate(HEMA)andN,N-dimethylacrylamide(DMAA),whichowngood biocompatibilityand hydrophilicityare involvedas hydrophic segment.Andthen PDMAAm-b-PDMS-b-PDMAAm, PHEMA-b-PDMS-b-PHEMA and PDMAAm star homo-polymerandPHEMAstarhomopolymercouldbeobtainedwithrelativelynarrowmolecular weightdistributi