bi系列可见光催化剂的制备及其催化降解性能分析word格式论文.docxVIP

优秀毕业论文 精品参考文献资料 摘要 下催化降解效果实验，降解效率分别为 85.23%、98.66%、87.25%和 82.75%；为 了考察不同单色光对降解的影响，我们利用单色光片分离出 6 种太阳光单色光， 分别是: 红、橙、黄、绿、蓝和紫光，测定其光强度，并在单色光照射下做了催 化剂 Bi7O9I3 对 2,4-D 的降解实验，6 种单色光的降解效率相差不大，其中紫光降 解率最高，达到 90.23%。研究结果表明合成的 BiOI、Bi4O5I2 和 Bi7O9I3 催化剂 具有很好的结构形貌和可见光吸收，可以很好的降解水中污染物，具有很好的 实际应用前景。 关键词：BixOyIz，亚甲基蓝，2,4-D，可见光催化，自然光催化 II Abstract Abstract Organic dyes and herbicides are main pollutants from modern production process emissions in water which have serious harm to environment and organisms, so the removal of these pollutants is more and more important. Green photocatalytic degradation technology becomes a research focus in the control environmental pollution because of its advantages of high efficiency and friendly to the environment. BixOyIz catalysts with different crystal morphology are prepared by hydrothermal method and oil bath in this paper. Globular BiOI and petals Bi4O5I2 catalyst is synthesized using hydrothermal, Bi7O9I3 with layered nanostructures is synthesized by using oil bath. The catalysts are characterized by XRD、SEM、UV-Vis DRS、XPS、BET. The results are as followed: 1. The results of XRD and SEM show that globular BiOI、 petals orbicular Bi4O5I2 and hierarchical nanostructures Bi7O9I3 dont have a lot of impurity peak which indicate that the catalysts are purity. 2. The UV – Vis show that BiOI, Bi4O5I2 and Bi7O9I3 have good absorption in the visible area, and the maximum absorption wavelength and most forbidden band width are 673 nm, 640 nm, 630 nm and 1.84 eV, 1.93 eV, 1.97 eV respectively. 3. The BET indicate that specific surface is 8, 12 and 18m2/g respectively. 4. The results of XPS about Bi4O5I2 show that three elements mole ratio is 3.7: 5.2: 1.6 and the chemical bond are + 3, - 2, -1, which demonstate this kind of material is Bi4O5I2. Before the photocatalytic degradation, the dark adsorption experiment is operated, and the results are simulated by the Langmuir and Freundlich isothermal adsorption model. The adsorption of MB by BiOI accord wi