bnti团簇结构演化和ymsi@al12团簇贮氢性能word格式论文.docxVIP

化学沉积法制备 CuInS2 薄膜及性能研究and the band gap of materials has obvious change.Deposition of In2S3/Cu2S composite films with one step and preparation and characterization of CuInS2 thin films.In the second section, the composite thin films of Cu2S/In2S3 was deposited in two steps, the procedure is complex comparatively. In the third section, we tried to prepare the composite thin films of Cu2S/In2S3 in one step. Firstly the composite thin film of Cu2S/In2S3 was deposited in a mixed solution of three hydrated nitric acid copper, thioacetamide and indium sulfate. The composite thin films were treated through the vulcanization annealing processing, forming CuInS2 films. The effect of annealing temperatures on the morphology, structure and optical property was also studied. The results show that the film presents a chalcopyrite structure. With the increase of annealing temperature, the crystallization increases and the grain size increases gradually. The absorption in visible light region becomes wider, and the band gap of materials decreases. Since t the adhesion is poor and the reaction is too long, the reaction temperature was increased to 45 oC. The composite thin films were obtained in two hours, and the CuInS2 thin films withchalcopyrite structure were fabricated after vulcanization annealing processing.Key words:chemical deposition method, CuInS2 thin film, vulcanization annealingivv绪论第一章 绪论随着人类社会的发展和文明的进步，越来越多的问题接踵而至。在诸多的矛盾中， 化石能源的过度依赖及其即将枯竭成为了主要矛盾；同时，随着经济发展，传统能源对 环境造成的污染日益严重，导致了全球性室温效应、干旱、沙漠化、空气污染等一系列 严重后果，成为了未来人类社会发展的重要障碍。进入 21 世纪，当电力、煤炭、石油 等不可再生能源频频告急，能源问题日益成为制约国际社会经济发展的瓶颈时，越来越 多的国家开始实行“阳光计划”，开发新的能源，寻求经济发展的新动力。世界各国都 在为发展可再生能源而做着大量的工作和努力，以期寻找到可以替代的新能源。一直以 来人们都在尝试着风能、潮汐、氢能、核能、太阳能等新型能源的开发和研制。这其中， 风能具有不稳定的缺点；潮汐的覆盖面太狭窄；氢燃料清洁环保，但储存不易，且安全 性能较难保证；核能具有较高的利用效率和美好的前景，但是俄罗斯切诺贝利核电站以 及近期日本福岛核电站的核泄露事故给人们展示了核能利用的安全隐患，核能依然存在 一定的使用风险。而太阳能因具有蕴藏量丰富、安全清洁、可再生、不会对环境产生负 作用等优点，成为世界各国重点发展的新型能源。因此，各国政府制定了一系列的长期 发展规划，使太阳能成为目前新能源研究的热点领域。最初人们利用单晶硅片制成电池模块，然后由众多的模块组装成较大面积的太阳能 电池板进行发电。到目前为止，其最高转换效率