cuingase四元化合物纳米晶有机碱辅助多元醇基溶液化学合成分析word格式论文.docxVIP

ABSTRACTCu(In,Ga)Se2(CIGSe) chalcopyrite compound is a leading light-absorbing material in the development field of thin film solar cells due to its unique optical and electric properties. In this dissertation, organoalkali-assisted polyol solution chemical synthesis was applied to prepare quaternary chalcopyrite CuIn1-xGaxSe2 nanocrystals (0≤x≤1). Synthetic reaction systems, organoalkali species, reaction temperatures, refluxing time, amounts of PVP, Se/(Cu+In+Ga) and Cu/(In+Ga) atomic ratios were investigated in order to optimize the processing parameters. The synthesized products were characterized by XRD, TEM/HRTEM, FESEM, EDX, UV-vis-NIR, ICP-MS, Raman measurements to probe phase crystallization, growing morphology, chemical composition and optical properties. Reaction mechanism was discussed according to the exprimental results, simultaneously, the organoalkali-assisted effects was qualitatively described based on the dynamic mechanism.The research results showed that triethylenetetramine, as an organoalkali assisting agent, was able to promote supersaturation balance among each individual element species and benefit the formation of target quaternary CIGSe compounds. Strong polarity of the solvent used and high synthetic temperature actually activated element Ga to participate the synthesis reaction. Based on the synthetic reaction process, a burst nucleation and early growth of quasi-ternary CuInSe2 were completed within 30 seconds during hot-injection process and Ga species reacted gradually as extending reaction time to form the quaternary CIGSe compounds finally. It is also seen that simply changing Se/(Cu+In+Ga) and Cu/(In+Ga) atomic ratios in feeding reaction solutions could not achieve well-controlled stoichiometry of nanocrystals synthesized. In addition, polyvinylpyrrolidone, as a dispersant, with small adding amount obviously enhanced the dispersing stability of nanocryatal products. In one word, triethylenetetramine-assisted diethylene glycol solut