c审审bnsialon及b4c陶瓷复合材料的制备及其组织与性能的研究word格式论文.docxVIP

用。XRD 分析表明，含 Si 试样的 B4C 晶格常数增大，这是由于 Si 取代 B4C 结构中 C-B-C 原子链的 C 原子并且 Si 可能会进入 B4C 晶体结构的空隙位置， 而且置换出来的 C 会与 Si 继续反应生成 SiC 相。在载荷为 20N 的干摩擦下，Si 含量为 4wt%、6wt%、10wt%的 B4C 复合材 料的摩擦系数在整个试验过程中一直以较大的 幅度波动，其波动范围为 0.3~0.6，这主要是由于随着摩擦磨损的进行，润滑膜和氧化膜相互交替；Si 含 量为 8wt%的 B4C 复合材料的摩擦系数曲线在整个试验过程比较平滑，其摩擦 系数为 0.2；且磨损率最低，为 1.75109×10-6mm-3/N·m，这是由于在摩擦磨损 过程中生成了 H3BO3 和 Si(OH)4 润滑膜。根据摩擦系数和磨损表面分析可知， 纯 B4C 和含 Si 的 B4C 复合材料在室温下干磨损机理为摩擦化学反应和化学诱 导断裂。关键词: 放电等离子烧结；SiAlON；c-BN；B4C；力学性能；摩擦磨损AbstractTo improve the sinterability of cubic Boron Nitride and Boron carbide, SiAlON and Si were added into c-BN and B4C, respectively, to supply transient liquid phase during the sintering. c-BN/SiAlON and B4C ceramic composites with high density were fabricated at low sintering temperature by SPS. The effect of composition and preparation process on the mechanical and wear properties of composites, the toughening mechanism and wear mechanism were studied.When the particle size of c-BN which used is 0.5~1μm, c-BN/α-SiAlON composites were prepared by spark plasma sintering. Over 70% c-BN hadtransformed to h-BN during the sintering at 1550℃for 5min. The added c-BNinhibited the formation of α-SiAlON, and the role of inhibition enhanced with the increasing of the content of c-BN. On the contrary, when using the larger size of c- BN (2~4μm), c-BN didn’t transforme to h-BN during the same sintering condition. The obtained Vickers hardness of the 20wt%c-BN/Yb-α-SiAlON composites could reach 21.586GPa.The Vickers hardness and the flexural strength of the c-BN /β-SiAlON composites with the c-BN size of 2~4μm increased with the increasing c-BN content. The composites containing 10wt% c-BN possessed the maximum mechanical properties. The HV and flexural strength are 15.4GPa and 432MPa, respectively. It is attributed to the crack deflection caused by c-BN particles. Subsequently, the mechanical properties decreased with the increasing c-BN content due to the low density.Wear tests were carried out under