合成锰氧化物对水中镍的吸附效能分析word格式论文.docxVIP

ABSTRACTHeavy metal nickel is a kind of carcinogen. When waste water with nickel is discharged directly into the water, not only threatening the aquatic organisms, but also destroying the ecological environment and endangering the human body health through the way of adsorption, precipitation and chain of food. The current main methods of treating heavy metals in solution includes adsorption technology, precipitation technology, ion exchange technology, biological technology and so on. Due to the wide application, simple operation and easy for mass production, the adsorption technology is considered to be an effective way to removal the heavy metals in the water. The metal oxide and hydroxide of iron, aluminum and manganese have porous structure, large specific surface area and be with a great amount of negative charge. Because of these characters, they have strong ability of adsorption for heavy metals and organic matters, using metal oxides as adsorbent to remove the pollutants in the water also arouse people’s interests.Manganese oxide are used as adsorbent. There are four different kinds of synthetic manganese oxides prepared and then screened out according to their adsorption performance for nickel in the water. The manganese oxides which are screened out are analyzed by X-ray diffraction (XRD) and Fourier Transform infrared spectroscopy (FTIR), and measure their point of zero charge (PZC). In the static adsorption experiments, through the way of controlling single factors to analyze their influences for adsorption. The main factors include the dosage of manganese oxides, pH values, ion concentration, temperature and initial concentration of nickel, adsorption time and so on. Meanwhile, analyzing the process of adsorption by the adsorption thermodynamics and adsorption kinetics. Conclusions are as follows:Four different kinds of chemosynthetic manganese oxides are prepared, they are α-MnO2, β-MnO2, γ-MnO2, δ-MnO2. Determining to use α-MnO2 and β-MnO2 as adsorbe