填料含量 导电性.pdf

料含量对石墨导电涂料表面电阻率的影响/顾安妍等 ·19 · 填料含量对石墨导电涂料表面电阻率的影响 1 1 1,2 2 顾安妍 ，张胜涛 ，高焕方 ，车向前 1 重庆大学化学化工学院，重庆 400044 ；2 重庆理工大学化学与生物工程学院，重庆 400050 ） 摘要 分别探索了以鳞片石墨、膨胀石墨和纳米石墨微片为导电填料，以丙烯酸树脂为基体的复合涂层的导电性能。 分析了 料的含量与涂层表面电阻率的关系。结果表明，以膨胀石墨为 料的涂层渗滤临界值最低， 料的含量相同时导电 效果最好，电阻率最低达20.8 /cm2 左右，在一定范围内几乎不随 料加入量而变化。 关键词 鳞片石墨 膨胀石墨 纳米石墨微片 导电涂料 表面电阻率 中图分类号：TQ638 文献标识码：A Effect of Content on the Surface Resistivity of Graphite Conductive Coating 1 1 1,2 2 GU Anyan ，ZHANG Shengtao ，GAO Huanfang ，CHE Xiangqian ( 1 College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044; 2 School of Chemical and Biological Engineering, Chongqing University of Technology, Chongqing 400050) Abstract In the present investigation，three acrylic resin/graphite conductive coatings are prepared with flake graphite, expandable graphite and graphite nanosheets as conductive filler, respectively, and using acrylic resin as matrix. The surface resistivity is tested, and the relationships of content and surface resistivity are investigated. Results show that the coating with 2 expandable graphite possesses a lower percolation threshold and a better electrical conductivity, reaching about 20.8 /cm , which is nearly independent of the amount on the expandable graphite. Key words flake graphite, expandable graphite, graphite nanosheets, conductive coating, surface resistivity 石墨作为导电涂料由于具有环境适应性好、密度小、价 板和不锈钢板上，在 70 下干燥 0.5h，制备分别含鳞片石