几种油田水用缓蚀剂的合成 评价及机理分析-synthesis evaluation and mechanism analysis of several inhibitors for water in oil fields.docx

AbstractThreenew3,5-dibromosalicylaldehydeSchiffbasecompounds（L1,L2,L3）andthreenew2-aminobenzimidazoleSchiffbasecompounds（D1,D2,D3）havebeensynthesizedandcharacterizedbyX-raydiffraction,ultraviolet-visiblespectrophotometry(UV-vis),infraredspectroscopy(IR),fluorescencespectra,thethermogravimetry(TG/DTG)andnuclearmagneticresonancespectroscopy(H1─NMR).Theweightlossmethods,electrochemicalmethods,scanningelectronmicroscopyandX-rayphotoelectronspectroscopywereperformedtostudythecorrosioninhibitionperformanceofsixSchiffbasesforcarbonsteelinoilfieldwater.TheweightlossmethodsandpolarizationcurvesmeasurementsshowthatsixkindsofSchiffbasecorrosioninhibitorshaveexcellentcorrosioninhibitionperformance,andtheinhibitionefficiencyofsixcorrosioninhibitorshavereached80%ormorewiththeconcentrationof75mg/L.Theorderofinhibitioncapacitywas:L2＞L1＞L3andD3＞D2＞D1,andallofthembelongtomixedtypecorrosioninhibitorwhichmainlyinhibitanodereaction.Electrochemicalimpedanceshowthatthevalueofchargetransferresistanceincreasedsignificantlyafteraddingcorrosioninhibitors,whichindicatethatcorrosioninhibitorshavegreatinhibitivepropertiesforcarbonsteel.Scanningelectronmicroscopyshowthatthecorrosiondegreeofcarbonsteelsurfacedecreasedgreatlyafteraddingcorrosioninhibitors.X-rayphotoelectronspectroscopyindicatethatthecorrosioninhibitormoleculescanpacktogetheroncarbonsteelsurfacetoformadensemonolayer.ThemoleculardynamicssimulationssoftwareMaterialsStudio5.5wasperformedtostudytheadsorptionprocessofthecorrosioninhibitormoleculesonFe(100)surfaceandthediffusenessprocessofcorrosionmediumparticlesincorrosioninhibitorfilm.TheresultsshowthatcorrosioninhibitormoleculescouldparalleladsorbedonFe(100)surfacewiththemannerofmulti-centerparalleladsorption.TheadsorptionrateofcorrosioninhibitormoleculeonFe(100)surfacesinvacuumisfasterthaninliquid.Theorderofadsorptionenergywas:L2＞L1＞L3，D3＞D2＞D1，andL3isslightlylargerthanD3.Thelargeradsorptionenergy,thebettercorrosioninhibitionperformanceisexhibited,whichcoincideswiththeresultsoftheele