尖晶石型mxco1-xfe2o4空心纳米球的制备和电化学催化性能及其在锂-空气电池上的应用-preparation and electrochemical catalytic performance of spinel mxco 1 - xfe2o4 hollow nanospheres and its application in lithium-air batteries.docxVIP

尖晶石型mxco1-xfe2o4空心纳米球的制备和电化学催化性能及其在锂-空气电池上的应用-preparation and electrochemical catalytic performance of spinel mxco 1 - xfe2o4 hollow nanospheres and its application in lithium-air batteries.docx

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尖晶石型mxco1-xfe2o4空心纳米球的制备和电化学催化性能及其在锂-空气电池上的应用-preparation and electrochemical catalytic performance of spinel mxco 1 - xfe2o4 hollow nanospheres and its application in lithium-air batteries

ABSTRACT尖晶石型MxCo1-xFe2O4空心纳米球的制备和电化学催化性能及其在锂-空气电池上的应用SynthesisandelectrocatalyticactivityofspinelMxCo1-xFe2O4hollowspheresascathodecatalystsinlithium-airbatteriesABSTRACTThispaperaimstoseekforbifunctionalcatalystswhichhavelowpriceandgoodcatalyticactivityfortheoxygenreductionreaction(ORR)andoxygenevolutionreaction(OER),whileCoFe2O4isakindoftransitionmetaloxideswhichhavebettercatalyticactivity.SothethesismainlyfocusesonthestudyofCoFe2O4hollownanospheresascathodecatalystinlithiumairbatteries.CoFe2O4hollownanosphereswerepreparedinthispaperbyasimpleandmildone-stephydrothermalmethod,andthepreparationofMxCo1-xFe2O4(M=Mn、Ni)hollownanospheresdopedwithMn/Niwereinthesameway.Bychangingtheholloworsolidstructuresorbydopingwithothermetalions,wetrytofindtheircorrelationswiththeelectrochemicalpropertiesofmaterialsforORRandOER,andtoexplorereasonsfortheimprovedcatalyticperformanceofmaterialsandmechanismsofcatalyticreactions.Inaddition,thecatalyticmaterialsofCoFe2O4hollownanospheresandthedopedCoFe2O4hollownanosphereswereusedaslithiumairbatterycathodecatalysts(ascatalyticmaterialsforairelectrode)andassembledintobatteriestostudydifferencesofthecatalyticperformanceofthesebatteries.Keywords:lithium-airbatteries;CoFe2O4;hollowspheres;doping;electrochemicalperformanceWrittenby:YujiaoXuSupervisedby:RuizhiYangJinghuaTianII目录中文摘要……………………………………………………………………………………IABSTRACT.........................................................................................................................II第1章绪论.........................................................................................................................11.1引言...........................................................................................................................11.2锂-空气电池.............................................................................................................21.2.1锂-空气电池的概述.......................................................................................21.2.2锂-空气电池的优势与面临的问题.................

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