锂电低压负极材料li1xv1-lithium battery low-voltage negative electrode material li1xv 1.docx

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锂电低压负极材料li1xv1-lithium battery low-voltage negative electrode material li1xv 1.docx

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锂电低压负极材料li1xv1-lithium battery low-voltage negative electrode material li1xv 1

AbstractThestrongdevelopmentofelectricvehiclesandportableelectronicdevicesdemandsforhigh-performancesecondarybatteries,andsomenewbatterymaterialstoaccommodatethehigherperformancearerequired.Nowadays,Thelithium-ionbatteriesisbeingconsideredasaverypromisingalternativeinpowerbatteryandenergystoragefieldwithhigheroutputvoltageandenergydensity.Li1+xV1-xO2asanewanodematerialscandidateforlithiumionbatteries,attractsmoreresearchersforitslowoperatingvoltageplatformandhigh-volumeenergydensity.Li1+xV1-xO2hasthesamelayeredstructureasthatofLiCoO2.Noconversionorreplacementreactionthroughlithiumion’sintercalationanddeintercalation,whichcanimprovethebatteryssafety.Unfortunately,issuesofLi1+xV1-xO2suchashighirreversiblecapacityatthefirstcycle,poorelectrochemicalperformanceinthehighratecycleandthemeetablemeetablexvalue,etcneedtobesolved.Inthiswork,Li1+xV1-xO2anodematerialispreparedbyasolid-statereactionmethod,andtheinfluencesofdifferentprotectiveatmosphere,temperature,andxvalueontheLi1+xV1-xO2physicalandelectrochemicalperformancearediscussed.Theprotectivegasdeterminesthepurityofthefinalproduct.Li1+xV1-xO2powdersarepreparedunderargon,hydrogenandwiththeratioof95:5.ItisfoundthatpureLi1+xV1-xO2canbeobtainedunderthemixtureofargonandhydrogenatmosphere,whileimpuritiesareobservedundertheothertwoatmosphere.ThebestperformanceofLi1+xV1-xO2isobtainedatx=0.1and800°C.Itsinitialdischargecapacityis301mAh·g-1at0.1C,and85mAh·g-1at1C.Variousamountsofcarbon-coatedLi1.1V0.9O2powdersarefabricated.Thebestperformanceisgovernedby5mass%carbon.Itsinitialdischargecapacityis301mAh·g-1at0.1C,anditdecreasesto124mAh·g-1after50cyclesand106mAh·g-1at1C.ThisishigherthanthatofLi1.1V0.9O2powderwithoutcarbon-coatedby31.8%.Keywords:Lithiumionbattery,Anodematerials,Li1+xV1-xO2,Carboncoating目录摘要..........................................................................................................................IABSTRACT.......................................................................................................