锂离子电池正极材料linil3col3mnl3o2与lini0.5mn1.5o4的制备及性能研究-preparation and performance study of linil 3c ol 3m nl 3 o 2 and lini 0.5 mn 1.5 o 4 as cathode materials for lithium ion batteries.docxVIP

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锂离子电池正极材料linil3col3mnl3o2与lini0.5mn1.5o4的制备及性能研究-preparation and performance study of linil 3c ol 3m nl 3 o 2 and lini 0.5 mn 1.5 o 4 as cathode materials for lithium ion batteries.docx

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锂离子电池正极材料linil3col3mnl3o2与lini0.5mn1.5o4的制备及性能研究-preparation and performance study of linil 3c ol 3m nl 3 o 2 and lini 0.5 mn 1.5 o 4 as cathode materials for lithium ion batteries

substituted, the initial capacity reduced，but the obtained capacity, cyclability, ratecapability would have been improved.Surface coating is an effective way to improve the performance of cathode materials. In this thesis, in order to improve LiNil/3Col/3Mnl/3O2 electrochemical performance by CuO-coated, the influences to LiNil/3Col/3Mnl/3O2 were studied with different doping ratio.The structure of the LiNil/3Col/3Mnl/3O2/CuO wasinvestigated by XRD，indicating that the lattice structure of LiNil/3Col/3Mnl/3O2 wasunchanged after the coating but the cycling stability, high rate capability and voltage cycling performance were improved. For LiNil/3Col/3Mnl/3O2/CuO, the discharge capacity was 154.5, 149.1, 137.4mAh/g at 0.5C, 1C, 2C rate in the special voltage window 2.5-4.3V, the capacity retained 94.9%, 92.9%, 92% after 10 cycles. The discharge special capacity was 198.2mAh/g at 0.2C rate in the voltage window 2.5-4.6V, the capacity retained 92% after 10 cycles.Spinel LiNi0.5Mn1.5O4 was synthesised by two-step solid-state method in the air. The effects of calcination temperature, time and annealing time on spinelLiNi0.5Mn1.5O4 cathode materials were studied. LiNi0.5Mn1.5O4 synthesised at 700℃for 18h and then annealing at 600℃ for 12h showed the highest first specificcapacity.Keywords：Lithium ion battery；layered LiNil/3Col/3Mnl/3O2；spinel LiNi0.5Mn1.5O4； doping modification；surface coating插图清单图 1-1 锂离子原理示意图 ·················································································· 3图 1-2 LiCoO2 的结构示意图6图 1-3 尖晶石锂锰氧结构示意图 ······································································· 7图 1-4 LiFePO4 的结构示意图9图 3-1 不同温度 LiNil/3Col/3Mnl/3O2 产品 X 射线衍射图样16图 3-2 煅烧不同时间合成的 LiNil/3Col/3Mnl/3O2 产品 X 射线衍射图样17图 3-4 不同锂比合成的 LiNil/3Col/3Mnl/3O2 产品 X 射线衍射图样20图 3-5 不同锂比合成的 LiNil/3Col/3Mnl/3O2 产品的首次放电曲线20图 3-6 不同锂比合成的 LiNil/3Col/3Mnl/3O2 产品的循环性能图21图 4-1LiNil/3Col/3 Mnl/3-xMgxO2（x=0.02，0.05，0.1，0.15）的 XRD 图23图 4-2LiNil/3Col/3 Mnl/3-xMgx