钌催化高锰酸钾氧化苯胺的效能及机理分析-efficiency and mechanism analysis of ruthenium - catalyzed oxidation of aniline by potassium permanganate.docxVIP

哈尔滨工业大学硕士学位论文了一种经济、有效的催化剂。关键词：高锰酸钾；苯胺；钌；催化氧化；负载AbstractAniline is a commonly used industrial chemical, which has been widely applied in the production of plastic, rubber, dyes, medicine, pesticide and so on. Along with huge amount of consumption is the increasing of aniline pollution in environment. Aniline is a kind of liquid in natural conditions, and has a relatively high solubility in water, which help it to enter natural water and cause threats to both biotope and human health through variety ways. Thus to find a safe, economical method of high efficiency is necessary. Permanganate is a green oxidant which has been used in water treatment for about fifty to sixty years, and has many applications. Based on the researches done before, permanganate couldn’t remove trace organic pollutants from water efficiently, and catalytic oxidation was found to be a promising way to solve this problem. Ruthenium is a kind of noble metal which has been used as catalyst in the production of synthetic ammonia, also in recent studies, it had been applied as catalyst during wet air oxidation process, and showed impressive effects. However few studies had focused on its application on permanganate oxidation system, especially at neutral pH. Therefore this study will use ruthenium as catalyst in aniline oxidation by permanganate system at neutral pH, try to figure out its impaction on this process and predict the mechanism during reaction.It’s proved that the addition of Ru(III) could significantly increase the reaction rate of aniline oxidation by permanganate; it is believed to have parallel paths of reaction in catalyzed system, and the kinetic equation could be written as: dC/dt=Kn[KMnO4][Aniline]+Kc[KMnO4]0.5[Aniline] [Ru(III)]。Results of thermo- dynamic study revealed that aniline oxidation by permanganate was an endothermic reaction. It was analyzed that thermodynamic constant under both conditions, which indicated that aniline molecules tended to combine together, and