高容量富锂正极材料li[li0.2ni0.2mn0.6]o2的制备与改性分析-preparation and modification analysis of high-capacity lithium-rich anode material li [ li 0.2 ni 0.2 mn 0.6 ] o2.docxVIP

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2018-06-01 发布于上海
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高容量富锂正极材料li[li0.2ni0.2mn0.6]o2的制备与改性分析-preparation and modification analysis of high-capacity lithium-rich anode material li [ li 0.2 ni 0.2 mn 0.6 ] o2.docx

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高容量富锂正极材料li[li0.2ni0.2mn0.6]o2的制备与改性分析-preparation and modification analysis of high-capacity lithium-rich anode material li [ li 0.2 ni 0.2 mn 0.6 ] o2

ABSTRACTWiththedevelopmentofthesocietyandeconomy,therequirementsofenergyandenvironmentalhavedeepened.Theproblemofenergycrisisespeciallyoilcrisisforcespeopletodevelopelectricvehiclesandnewenergytoreplacethenon-renewableenergy.Lithium-ionbatterieshavebeenconsideredasidealpowersourceelectricvehiclesandlarge-scaleenergystorageapplication.Althoughthetraditionallithium-ionbatterieshaveshownanimportantroleinsmalldevices,theystillcannotmeetthedemandforhigh-power,high-capacitystorage.theactualcapacityofcommercializedLiCoO2、LiNi1/3Co1/3Mn1/3O2、LiNi0.5Co0.2Mn0.3O2、Li2MnO4、LiFePO4islessthan200mAh·g-1,whichlimitsitsfurtherdevelopment.Recently,Lithium-richmanganese-basedsolidsolutionlithium-ionbatterieshavearousedmuchattentionforitshighcapacity.Inthisthesis,thelithium-richmanganese-basedcathodematerialsofthelithiumionsecondarybatteryxLi2MnO3·(1-x)LiNi0.5Mn0.5O2havebeenpreparedbyco-precipitation-calcination,andMg2+/Zn2+dopingandZnO/ZrO2coatingmodificationweredone.X-raydiffraction,scanningelectronmicroscopy,transmissionelectronmicroscopy,cyclicvoltammetry,impedancetest,andcharge/dischargetestofthesyntheticmaterialhasbeeninvestigated.Theworkisasfollows:TheprecursorMnaNib(OH)2wassynthesizedbyco-precipitation,mixedwithLi2CO3,andcalcinedtoobtainfinalLi-richcathodematerial.Theinfluencesoftheamountoflithium,calcinationtemperature,holdingtimeonthestructureandpropertiesofmaterialshavebeeninvestigated.Theresultsshowthatthelongertheheattreatmenttime,thehigherthetemperature,themorecompletedpolymorphcanbeobtained,andthelayeredstructureismoreobvious,butthisnotmeansagoodelectrochemicalperformance.Consideringthecost,efficiency,andtheelectrochemicalproperties,theoptimalconditionwasidentifiedas8%excesslithium,x=0.5,calciningat900oCandholding12h.TheeffectsofMg2+，Zn2+dopingonthestructureandperformanceofLi[Li0.2Ni0.2Mn0.6]O2cathodematerialhavebeenstudied.Dopingduringtheprecursorpreparationprocessandduringball-millingprocesswascompared.Differentdopingamountwasdiscussed.TheresultshowsthatbothMg2+andZn2+