高强低吸湿铝合金用水溶性型芯的分析-analysis of water soluble core for high strength and low moisture absorption aluminum alloy.docx
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高强低吸湿铝合金用水溶性型芯的分析-analysis of water soluble core for high strength and low moisture absorption aluminum alloy
Humidityresistanceimprovedbyprecipitationmethodwasinvestigated.Theresultsshowedthat:thehumidityresistanceofthewatersolublecoretreatedbyalcoholicsolutiondissolvedwithcalciumchloridewasimprovedprominentlyontheaccountoftheporoussurfacecoatedbycalciumchlorideandthehighhumidityresistanceproductsgeneratedinthereactionbetweencalciumchlorideandpotassiumcarbonate;undertheconditionofRH=75~85%,T=20~25℃,thestrengthlossofthewatersolublecoretreatedbypreipitationmethodwas15%,whichwas30%ofthatwithoutanytreated.Thefomularofthewatersolublecoreusedinalluminumcastingwithhighstrengthandlowhygroscopicitywasobtainedandthemechanismofthecolapsibilitywasinvestigated.Theresultshowedthat:thecoremadeofthefomularwithhighstrengthandlowhyproscopicityhadhighstrength(2.5Mpa),lowgasevolution(6.2mL/g),andgoodcolapsibilityandhumidityresistance;potassiumcarbonateandsilicasandcouldsinterat600~800℃,butthesinteringreactionwasinsufficiencyandtakesplaceatthesolid-solidcontactbetweenpotassiumcarbonateandsilica,socoreswithoutstrengtheninghadgoodcolapsibilityonaccountofitsporousstructureandthepropertyofpotassiumcarbonatesolubleinwatereasily;strengtheningmaterialscouldnotreactwithpotassiumcarbonate,sotherewasnonewsinterreactioninstrengtheningcores,whichguaranteedthatstrengtheningcoresalsohadgoodcolapsibilities.Keywords:watersolublecore;potassiumcarbonate;strengthening;pricipitationmethod;humidityresistance;mixturedesign独创性声明本人声明所呈交的学位论文是我个人在导师指导下进行的研究工作及取得的研究成果。尽我所知,除文中已经标明引用的内容外,本论文不包含任何其他个人或集体已经发表或撰写过的研究成果。对本文的研究做出贡献的个人和集体,均已在文中以明确方式标明。本人完全意识到本声明的法律结果由本人承担。学位论文作者签名:日期:年月日学位论文版权使用授权书本学位论文作者完全了解学校有关保留、使用学位论文的规定,即:学校有权保留并向国家有关部门或机构送交论文的复印件和电子版,允许论文被查阅和借阅。本人授权华中科技大学可以将本学位论文的全部或部分内容编入有关数据库进行检索,可以采用影印、缩印或扫描等复制手段保存和汇编本学位论文。本论文属于保密□,在年解密后适用本授权书。不保密□。(请在以上方框内打“√”)学位论文作者签名:指导教师签名:日期:年月日日期:年月日1绪论1.1研究背景及意义由于铝合金铸件重量轻、色泽美、耐腐蚀性好,因此在当今世界铸件的构成中,已经越来越引人注目。非鉄合金铸件的产量在迅速增加,而铁合金铸件的产量在铸件的总产量构成比例中则出现了下降的趋势。其中,国内外航空、航天、汽车、船舶、兵器、电子等行业为追求零部件结构合理,达到轻量化、薄壁化,正在大力发展大型、复杂、薄壁、整体的铝合金精密铸件[1]。中国汽车工业协会发布的统计数据表明,2010年中国汽车产销量双双突破1800万辆,不仅蝉联世界第一,且创
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