微生物燃料电池论文：微生物燃料电池阴极材料的制备及其产电性能研究.docVIP

微生物燃料电池论文：微生物燃料电池阴极材料的制备及其产电性能研究 【中文摘要】微牛物燃料电池(MFCs)是一种环境友好的生物产电技术,能利用微生物将有机底物中的化学能通过电化学反应直接转换为电能,具有原料广泛充足,操作条件温和,清洁环保等特点,在缓解能源短缺和环境问题方面具有巨大潜力。但是MFCs仍存在不稳定、效率不高、输出功率低、成本昂贵等问题,阻碍了其进一步发展。本文针对MFCs输出功率低、成本高等问题,先后制备了两种类型的阴极材料,同时相对应地改变了电池构型,设计和搭建实验室平台,并从材料性能,输出功率和运行情况等方面对MFCs体系的产电性能进行对比研究,进而对影响电池产电性能的因素进行分析和优化。论文的研究内容主要包括以下几个部分：1、使用发散法制备了4.0代树状大分子,通过季胺化反应得到表面带正电荷的部分季胺化树状大分子,并且以此为模板,通过硼氢化钠 【英文摘要】Microbial fuel cells (MFCs), one type of environmental friendly bio-technology, represent a device that transforms chemical energy in organic materials directly into electrical energy via electrochemical reactions. With the advantages of abundant fuels, mild operation condition and clean green, the MFCs have great potential in dealing with the supply of fossil fuels decline and environmental problems intensify. The instability, inefficiency, low power output and high cost are still the major drawbacks in the development of MFCs.According to low output and high cost of the MFCs, we prepared two types of cathode material and changed the configuration correspondingly. The experimental platform was designed and set up to research the material property, power output and operation condition. Then, compared and analyzed these factors to find and optimize the electrogenesis performance of MFCs. The thesis including the following parts:1、Generation 4.0 Partially quarternized Polyamidoamine (PAMAM) dendrimers with both quaternary ammonium groups and primary amines was prepared. Using template synthesis method, after the reduction reaction, we are able to produce Polyamidoamine (PAMAM) dendrimer encapsulated Platinum nanoparticles (Pt-DENs) with uniform diameters of 4 nm. Meanwhile, electrodeposition of Pt on carbon paper was performed in three-electrode system:Pt wire and Ag/AgCl were used as counter and reference electrodes while carbon paper serves as working electrode. Pt nanoparticles deposited and dispersed uniformly on the whole surface of the carbon paper with a diameter of 300 nm.2、A