新型ni-co基变形高温合金的成分设计与组织性能关系-relationship between composition design and microstructure and properties of new ni - co based wrought superalloys.docx

金中，适当提高 Ti 含量可以提高合金中 γ′相的含量和?γ/γ′相的晶格错配度，增加合金的析出强化效果，但是 Ti/Al 值过高会增加合金中 η 相析 出，不利于合金高温服役时的组织稳定。制备四种 Al、Ti、Co 元素含量不同的 Ni-Co 基高温合金。实验表 明，新型 Ni-Co 基高温合金具有良好的加工能力，在合适的温度区间 内可以进行轧制等变形处理。合金经过轧制变形后，枝晶破碎，合金 中的组织均匀性明显提高。合金进行固溶处理和两次时效处理后，可 以得到弥散分布于基体的一次 γ′析出相和尺寸更细小的二次或三次 γ′ 析出相。对四种 Al、Ti、Co 元素的含量不同的 Ni-Co 基高温合金的微观组 织进行分析后发现，在 Ti/Al 值为 1.8 的合金中，铸态和轧制态均析出 了一些板条状 η 相，而在其它几种 Ti/Al 值较低的合金中没有 η 相析 出。在不同温度下对合金进行拉伸实验后发现，在 750℃及以下温度 区间内，Ti/Al 值和 Ti+Al 含量较高的合金具有良好的拉伸屈服强度。 但是在 750℃以上，Ti/Al 值较高的合金屈服强度随温度升高明显下降， 而 Ti+Al 含量较高的合金仍能保持较高的屈服强度。因此在 Ni-Co 基 变形高温合金中可适当提高 Ti+Al 含量，但应严格控制 Ti/Al 值。关键词：Ni-Co 基变形高温合金，JMatPro 热力学计算，γ/γ′相晶格错 配度，TCP 相，加工窗口，高温力学性能THERMODYNAMIC DESIGN AND ITS MICROSTRUCTURE-PROPERTY RELATIONSHIP OF A NOVEL Ni-Co BASE SUPERALLOYABSTRACTIn order to increase the operation temperature of nickel base superalloys to meet the need for increased efficiency of airplanes engines, some refractory elements like Mo, W are added to increase the solution strengthening. The alloys with high contents of these elements, however, often exhibit poor process-ability so that they have to be produced by powder metallurgy, resulting in unacceptable cost and density. Besides, excessive use of such refractory alloying elements aggravates segregation which promotes the precipitation of some TCP phases and degrades the mechanical properties of superalloys. These drawbacks limit the application of superalloys. Therefore, the superalloys strengthened by suitable Al, Ti and Co contents have been developed. These alloys have not only improved mechanical properties at high temperature, but also broad working window. In this paper, new Ni-Co base superalloys, which are strengthened by Co3Ti have been studied to investigate the effects of Ti, Al and Co elements on the mechanical properties and work-abilities by thermodynamic calculation and experiments.Firstly, the effects of the Ti, Al and Co elements on the equilibrium precipitations, alloys’ work-ability and γ/γ′ misfit have been studied by thermodynami