新型多孔颗粒的制备及其主流烟减害效果的分析-preparation of new porous particles and analysis of the harm reduction effect of mainstream smoke.docxVIP

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2018-06-03 发布于上海
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新型多孔颗粒的制备及其主流烟减害效果的分析-preparation of new porous particles and analysis of the harm reduction effect of mainstream smoke.docx

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新型多孔颗粒的制备及其主流烟减害效果的分析-preparation of new porous particles and analysis of the harm reduction effect of mainstream smoke

同时，本试验也将改性活性炭添加到卷烟滤嘴中，研究了其对主流烟的减害效果，并与活性炭原样进行了比较分析。卷烟烟气吸附实验结果表明，改性活性炭对主流烟气中的 CO、HCN、4-（甲基亚硝胺）-1-（3-吡啶基）-1-丁酮（NNK）、B[a]P、苯酚、巴豆醛等有害成分的去除率基本高于活性炭原样，去除效果较好。其中，水含量为 6.5 wt%时所得改性活性炭的去除效果相对最好，对 B[a]P、N-亚硝基去甲基烟碱（NNN）等烟气中的主要致癌物的去除率相对活性炭原样分别提高了 5.4 %和 6.3 %。关键词：活性炭，醋酸纤维素，非溶剂致相分离，吸附IIPreparation of novel porous particle and the study of its harm reduction effectiveness for mainstream smokeAbstractAs one kind of excellent adsorbents, activated carbons (AC) have been widely used in sugaring, medicine, food, chemical engineering and other industries. So far, among all the additives in cigarette filter, AC is the most widely used and the most effective one. Its contribution in reducing tar and harmful chemicals from mainstream cigarette smoke should not be underestimated. However, AC filter also has some disadvantages, such as the influence on the flavor of the cigarette products. AC filter can remove certain harmful chemicals from mainstream cigarette smoke as well as some aroma components which can result in insufficient of aroma. At present, adding essence is the mainly solution to overcome this problem. The researches that specialize in the modification of AC to solve this problem are rarely reported. In our country, most of the researches on AC used in cigarette filter are focus on that the reducing of tar, phenolic compounds, part of carbonyl compounds and other harmful chemicals without deeply into micro-level. And seldom do the research on the adsorption effect of AC from its pore structure and surface chemical properties. Therefore, to find a sort of AC with specific pore structure which can remove more of harmful chemicals from mainstream smoke and does not influence the flavor of cigarette is particularly important.This paper discusses a new modification method to endow AC with selective adsorptivity. Basing on the findings of nonsolvent induced phase separation from a cellulose acetate (CA) ternary solution in a mixed solvent of acetone and water, we successfully co