新型功能化聚烯烃三嵌段共聚物的合成及性能分析-synthesis and property analysis of novel functionalized polyolefin triblock copolymers.docxVIP

关键词：聚烯烃功能化，嵌段共聚物，自组装，温度响应性，聚合物微孔膜，聚合物微球，共混IIAbstractThe design and synthesis of block copolymers incorporating polyolefins segments and other more polar segments could broaden the scope of application of polyolefins greatly and it has become one of hot topics in the functionalization of polyolefin in recent years. In addition, among the countless stimuli-responsive polymer, temperature-responsive polymer is the most interesting intelligence material for its broad application prospects in many areas. In this thesis, two kinds of well-defined temperature-responsive triblock copolymers based on polymethylene were synthesized via the combination of living polymerization of ylides and reversible addition-fragmentation chain transfer polymerization (RAFT). The molecular structure and weight of all the polymerization products were characterized. Furthermore, the properties of the both triblock copolymers in self-assembly, preparation of microporous polymer films and polymer blends were investigated. The content of this study can be divided into the following sections:Well-controlled functional polyolefins block copolymers PM-b-PNIPAM and PM-b-PNIPAM-b-PS were obtained by RAFT polymerization. Firstly, hydroxyl terminated polymethylene (PM-OH, Mn=1100, Mw/Mn=1.09) was prepared via polyhomologation of ylides. Then the macromolecular chain transfer agent (PM-CTA) was obtained via an esterification of smallmolecular chain transfer agent (CTA) with PM-OH. A series of PM-b-PNIPAM diblock copolymers were obtained by RAFT polymerization of NIPAM using PM-CTA as chain transfer agent. Subsequently, PM-b-PNIPAM-b-PS triblock copolymers were prepared via RAFTpolymerization of styrene. The 1H-NMR, FT-IR and GPC were employed todetermine the chain structures, molecular weight and molecular weight distributionsof all the polymerization products.A series of functional polyolefins PM-b-PS and PM-b-PS-b-PNIPAM copolymers were prepared by RAFT polymerization as above and their chain