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卟啉钴共同物的设计、合成及其催化CO2与环氧环己烷共聚行为的研究
卟啉钴配合物的设计、合成及其催化 CO2 与环氧环己烷共聚行为的研究
2.4.4 聚合物的核磁谱图数据[88] ·········································22
2.5 四苯基氯化钴催化CO /CHO 共聚行为的研究 ·························23
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2.5.1 温度对聚合反应的影响·············································24
2.5.2 主/助催化剂配比聚合反应的影响 ································25
2.5.3 反应时间对聚合的影响·············································26
2.5.4 主催化剂用量对聚合的影响·······································27
2.5.5 压力对聚合的影响···················································28
2.5.6 溶剂对聚合的影响···················································28
2.5.7 主催化剂轴向负离子对聚合的影响······························29
2.5.8 助剂 PPNCl 对聚合的影响 ·········································30
2.6 四种不同取代四苯基氯化钴催化CO /CHO 共聚行为的研究 ·······31
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2.7 本章小结·······································································32
第3 章 超临界CO 聚合体系中分散剂的溶解行为研究·························33
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3.1 引言 ·············································································33
3.2 实验部分········································································34
3.2.1 试剂与仪器····························································34
3.2.2 溶解度测试····························································35
3.3 结果与讨论·····································································35
3.3.1 溶解度的测试 ························································35
3.3.2 Bartle 模型的计算与关联···········································36
3.3.3 Chrastil 模型的计算与关联 ········································38
3.3.4 溶质偏摩尔体积的计算 ············································39
3.4 本章小结········································································40
结 论························································
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