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北京服装学院硕士研究生论文 摘 要 本论文尝试了一种新的聚合工艺 即在有机颜料表面直接合成并 覆盖高分子分散剂 对有机颜料进行表面处理 改善其在水性体系中 的分散性 实验证明 该工艺是可行的 论文对该工艺进行了初步探 讨 通过改变工艺条件 改进颜料的研磨工艺 选择合适的亲水单体 及疏水单体 确定单体及引发剂的最佳用量 调整反应温度 反应时 间 搅拌速度等聚合条件 对难分散的酞菁绿颜料进行表面处理 经分散稳定性 扫描电镜等测试表明 该工艺可明显提高颜料在水中 的分散稳定性 将该聚合工艺处理的效果与国外水性颜料分散剂的处 理效果进行比较 发现本工艺处理颜料的分散性已达到国外分散剂处 理的分散性 对热的稳定性明显优于国外分散剂的处理结果 贮藏稳 定性略差于国外分散剂处理效果 但有望通过工艺条件的进一步调整 得到改进 关键词 水性体系 有机颜料 表面处理 聚合 分散稳定性 北京服装学院硕士研究生论文 Abstract In this paper, a new technology for the surface treatment of organic pigments has been experimented with to improve the pigments disperbility in water borne systems, which is to directly synthesize and cover polymer dispersing agents on the pigment surface by polymerization. It has been proved by experiments that this technology is feasible. Thesis has discussed elementarily this technology. Phthalocyanine Green is hard to disperse. By changing the technology conditions, which are to improve milling technology, select suitable hydrophobic monomers and hydrophilic monomers, confirm the optimum consumption of monomers and initiators, adjust reaction temperature, reaction time and stirring speed and so on, the disperbility and stability of modified Phthalocyanine Green have been greatly improved through the test of dispersibility and the microscopic analysis. Comparing the effect of handling by our technology with that by imported surfactants, the disperbility of pigments treated by our technology has been reached the level of treating by surfactants, the stability to heat is superior to that by surfactants, and the stability to preservation is not so good as that by surfactants, but it will be improved by adjusting further technology conditions. Keywords: water borne systems; organic pigments;