负载型铁基复合氧化物催化剂制备及性能的研究.docVIP

毕业设计(论文)中文摘要 负载型铁基复合氧化物催化剂制备及性能研究 摘要: 本论文通过直接水热浸渍法，将硝酸铁、硝酸锰和硝酸钬以不同比例混合，并制备出的负载型铁基复合氧化物催化剂。通过红外测试对催化材料的影响，通过活性测试分析负载型催化剂的脱硝效率。 实验结果表明介孔材料KIT-6与稀土元素Ho对铁基催化剂的催化性能有很大的影响，它们的添加大大增加了SCR脱硝反应所需的活性位，进而提高中温脱硝效率。当负载型催化剂比例为40%Fe3Mn4Ho1Ox-KIT-6时，在℃-280℃温度区间内脱硝效率高达0%。这对于汽车尾气的处理，以及烟煤厂的脱硝是技术的升级，价格低廉更易让广大用户接受，对于改善大气有重大意义。 KIT-6负载 选择性催化还原 铁基复合氧化物 脱硝催化剂毕业设计(论文)外文摘要 Title: Study on Preparation and Properties of Supported Iron -based Composite Oxide Catalysts Abstract In this paper, a series of iron-based composite oxide catalytic active components were prepared by mixing Fe(NO3)3·9H2O, 50%Mn(NO3)2(l) and Ho(NO3)3·5H2O in different proportions.Combining KIT-6 with the best active components to study the catalytic performance and the SCR denitration mechanism of the supported catalysts.The effect of Ho element and the structure of KIT-6 on the crystal phase of the catalytic material were studied by XRD and IR.The denitrification ability of the supported catalyst was analyzed by the activity test. The results showed that KIT-6 and Ho increased the active sites required for SCR denitrification and improved the denitrification of medium-temperature.When the supported catalyst ratio is 40% Fe3Mn4Ho1Ox-KIT-6, the prepared catalyst had the widest window compared with others.In the temperature range of 200 ℃ -280 ℃, the denitrification efficiency is as high as 80%.It is important to study the iron-based composite oxide catalytic for processing exhaust, the denitration technology upgrading and improving surroundings, and low prices easily accepted by users. Keywords: KIT-6 selective catalytic reductio Iron-based composite oxide catalyst denitrification 目 录 1 引言 1 1.1 烟气脱硝技术研究背景 1 1.2 脱硝技术国内外研究现状 1 1.2.1 贵金属催化剂 2 1.2.2 非贵金属氧化物催化剂 2 1.2.3 分子筛催化剂 4 1.2.4 铁基SCR脱硝催化剂的研究现状 4 1.3 脱硝催化剂的制备方法 5 1.4 铁基复合物催化剂SCR脱硝机理研究现状 7 1.4.1 钬掺杂对铁氧化物催化剂脱硝性能的反应机理 8 1.4.2 催化剂载体机理 8 1.5 研究目的与意义 9 2 实验部分 9 2.1 实验药品 9 2.2 实验仪器 10 2.3 负载型铁基复合氧化物催化剂的制备 10 2.3.1 制备介孔KIT-6 10 2.3.2 铁锰钬复合物与KIT-