PES纳米纤维制备工艺研究.docx

xx大学毕业设计（论文）  PAGE \* MERGEFORMAT VII PES纳米纤维的制备工艺研究  PAGE \* MERGEFORMAT VIII PES纳米纤维的制备工艺研究 摘 要 聚醚砜(PES)具有良好的化学和水解稳定性，强度高，pH值适应范围广，最高使用温度达129 ℃，抗氧化性和抗氯性均十分优良，因此已成为重要的膜材料之一。它的特性有：耐热等级髙、机械性能好、尺寸稳定性好、电性能优异、阻燃性好、易成型加工等，经过几年的开发，聚醚砜已在许多工业领域得到广泛的应用，比如电子工业、机械工业、航空工业、汽车工业、医疗食品工业等。 本文采用静电纺丝技术制备PES纳米纤维，运用光学显微镜（OM）和扫描电子显微镜（SEM）观察纤维。主要研究材料制备过程中质量分数、纺丝电压、接收距离等因素对PES纤维形貌、尺寸、均匀度的影响。 实验得出：研究17%、19%、20%、22%PES质量分数的样品和17kV、19kV、21kV纺丝电压得到的样品中，得出：一定条件下，质量分数20%以下无法纺丝成纤维丝；一定条件下，质量分数为20%和22%的纺丝纤维丝的平均直径分别为444nm，547nm，标准差分别为356、556，说明一定条件下随着质量分数的提高，纤维平均直径增大，离散度减小；一定条件下，纺丝电压为17kV、19kV、21kV的样品平均直径为444nm、435nm，标准差为356、415，说明一定条件下随着纺丝电压的提高，纤维平均直径减小，离散度增大。 关键词：纳米纤维；静电纺丝；聚醚砜 study on preparation of PES nanofibers via electrospinning Abstract Polyether sulfone (PES) has good chemical and hydrolysis stability, high strength, wide PH range (PH) 1 ~ 13, the highest working temperature of 129 ℃, oxidation resistance and the resistance to chloride are very good, therefore has become one of important membrane materials. Its features are: heat resistant level high, good mechanical properties and good dimension stability, excellent electric properties and flame retardancy, easy processing, etc., after years of development, poly (ether sulfone) has been widely used in many fields of industry, such as the electronics industry, machinery industry, aviation industry, automobile industry, medical and food industry etc. This paper USES electrostatic spinning to prepare PES nanofibers, using an optical microscope (OM) and scanning electron microscopy (SEM) to observe fibers. By electrostatic spinning technology of preparation of polyether sulfone nanofibers, the main research mass fraction in the process of material preparation, spinning voltage, voltage, receiving distance on the PES fiber morphology, size and evenness. Experiment: 17%, 19%, 20%, 19% PES mass fraction and 17kV, 19kV, 21kV spinning voltage to get the samples, some conditions, the mass fraction below20% ca