碱性条件下制备CdTe薄膜电池机制研究.docxVIP

xx大学毕业论文 — PAGE \* MERGEFORMAT VII— 毕业论文 题 目 有机强碱溶液体系电沉积 CdTe薄膜及相关机制研究 摘 要 CdTe薄膜太阳电池是以p型的CdTe和n型的CdS的异质结为基础的太阳电池。CdTe薄膜的禁带宽度为1.45eV，吸收波长为855nm，与太阳光谱非常匹配；具有很高的光吸收系数，在可见光范围内高达104cm-1，2μm厚的碲化镉薄膜能吸收99%以上的太阳光；同时还具有高的转换效率，其理论光电转换率高达30％。本实验采用电化学沉积法制备CdTe薄膜，主要研究有机强碱溶液中电沉积CdTe薄膜机理及其影响因素。 本实验采用循环伏安法来探究碲化镉薄膜的沉积机理，同时通过对有机碱性溶液的循环伏安曲线分析，探究pH、温度、Cd2+浓度和NTA和Cd2+络合比对沉积过程的影响。通过循环伏安曲线分析可知，较低的pH促进TeO32-在CdS薄膜表面进行吸附，有利于CdTe的沉积，能使CdS与CdTe的接触更加良好；由于反应为欠电位沉积，较高的温度能为反应提供足够的能量，但过高的温度会使CdTe薄膜的结晶度改变，使CdTe结晶度更好，电阻率降低，利于接下来的沉积；高浓度的Cd2+对TeO32-的吸附有抑制作用，同时Cd2+浓度过高时，会使溶液中存在自由Cd2+，高温下大量水解会降低pH；浓度过高或过低的NTA都不利于沉积CdTe薄膜,会导致CdTe薄膜中Te过量或Cd过量。通过X射线衍射仪、场发射扫描电子显微镜、X射线能量分散谱仪等仪器对沉积的CdTe薄膜进行表征，得出络合比为8:1时，CdTe薄膜结晶度最好，取向为立方的（111），同时碲镉原子比与化学计量比最为接近，但CdS与CdTe接触面不良，接触面最佳的络合比为16:1。 关键词：CdTe薄膜太阳电池；有机碱性溶液；电化学沉积；沉积机理；络合比  ABSTRACT CdTe thin film solar cells are based on p-type CdTe and n-type CdS heterojunction-based solar cells.The band gap of CdTe film is 1.45eV, the absorption wavelength is 855nm, which matches the solar spectrum very well.With a high light absorption coefficient, in the visible range up to 104cm-1,2μm thick cadmium telluride film can absorb more than 99% of the sun;But also has a high conversion efficiency, the theoretical photoelectric conversion rate as high as 30%. In this experiment, CdTe thin films were prepared by electrochemical deposition. The mechanism of electrodeposited CdTe films in organic alkali solution was studied.In this study, cyclic voltammetry was used to investigate the deposition mechanism of cadmium telluride thin films. At the same time, the cyclic voltammetry curves of organic alkaline solutions，The effects of pH, temperature, Cd2+ concentration and NTA and Cd2+ complexation on the deposition process were investigated.By cyclic voltammetry analysis, it can be seen that the lower pH promotes the adsorption of TeO32- on the surface of CdS film, which is favorable for the deposition of CdTe, which makes the contact of CdS and CdTe better.Since