2370.熔分渣脱硫工艺实验的研究.docVIP

XXX学院本科毕业设计(论文) 熔分渣（富钛料）脱硫工艺实验研究 学生姓名： 学生学号： 院 （系）： 材料工程系 年级专业： 级材料科学与工程 指导教师： 教授 助理指导教师： 二〇〇七年六月 摘 要 钛铁精矿经转底炉金属化还原后，再经电炉熔化分离所得的渣（熔分渣）中富含有TiO2，这种渣用途广泛，可作为硫酸钛白、电焊条及钛铁生产的原料，品位提高后也可用作氯化钛白生产。但它们对熔分渣中的杂质含量有特殊的要求，特别是对硫杂质含量一般要求控制在0.03%以下。 本实验研究采用高温氧化焙烧脱硫法，研究焙烧温度、焙烧时间、焙烧气氛、熔分渣粒度等主要因素对脱硫效果的影响，以及采用数字光学显微镜、同步TG-DTA/DSC分析仪、XRD研究熔分渣脱硫前后的微观形貌、结构和成分的变化。 实验结果表明：在1130℃、50min、40目左右、在通入氧气的气氛时脱硫效果最好，控制氧气流量在0.3Nm3/h左右时脱硫率可达到94%以上；脱硫前熔分渣主要存在FeS、Ca4Ti3O10、CaMg2、TiO2和CaTi2O4等化合物，脱硫后硫化物和TiO2不存在了，出现了一些更为复杂的钛酸化合物。  ABSTRACT When titaniferous iron concentrate is metallized reduced in rotary hearth furnace and separated by melting, the slag is rich in TiO2.The material is widely used such as sulfuric acid、welding electrodes and TR production of raw materials. After raising the grade, slag also be used in the production of titanium dioxide.The content of impurities,，in molten slag are specially required.Generally,the required content of sulfur is below 0.03%. In this experiment, we use high temperature oxidation roasting desulfurization method to desulfurization. The effects of The roasting temperature , roasting time, roasting atmosphere ,the granularity of molten slag and other factors on desulfurization are studied. Before and after molten slag are desulfurized , the microscopic morphology, microscopic structure and the changes of composition are tested by digital optical microscope、Synchronous TG-DTA/DSC analysis、XRD. Experimental results show that when the experimental parameters are 1300℃、50 min、40 mesh size and passing oxygen, desulfurization is best. When the flow of oxygen is 0.3Nm3/h, the desulfurization rate could reach more than 94%; the original slag samples mainly contain FeS、Ca4Ti3O10、CaMg2、TiO2、CaTi2O4 and other compounds. After original slag samples are sulphidized, sulphides and titanium dioxide does not exist，but some more complex barium compounds appears to