Fourier ransform IR Spectroscopy傅里叶变换红外光谱.pptVIP

Fourier Transform IR Spectroscopy Saptarshi Basu Introduction Absorption peaks in an infrared absorption spectrum arise from molecular vibrations Absorbed energy causes molecular motions which create a net change in the dipole moment. What is FTIR Fourier-transform infrared spectroscopy is a vibrational spectroscopic technique, meaning it takes advantage of asymmetric molecular stretching, vibration, and rotation of chemical bonds as they are exposed to designated wavelengths of light. Fourier transform is to transform the signal from the time domain to its representation in the frequency domain Theory and Instrumentation Theory and Instrumentation(contd.) The light originates from the He-Ne laser Half of the light is reflected 90 degrees and hits a fixed mirror, while the other half passes through the beam splitter and hits the moving mirror The split beams are recombined, but having traveled different distances, they exhibit an interference pattern with each other As they pass through the sample, the detector collects the interfering signals and returns a plot of response v. mirror displacement known as an interferogram Mathematics Mathematics (contd.) The resulting interferogram is described as an infinitely long cosine wave where =intensity as F(v) For non-monochromatic source treat each frequency as if it resulted in a separate cosine train. Mathematics (contd.) An infrared source is typically approximated as a black body radiator and the summation can be replaced by an integral. At = 0, signal always has a strong maxima called Centreburst Outwards from the centreburst the cosine waves cancel and reinforce and the amplitude of the interferogram dies off. Mathematics (contd.) Spectroscopists are interested in the spectrum in the frequency domain i.e intensity versus wavenumber If the mathematical form of the interferogram is known,spectrum