渗透反应栅技术处理铀矿山酸性废水室内试验研究.docVIP

研究生毕业论文中文摘要首页用纸 毕业论文题目：渗透反应格栅技术处理铀矿山酸性废水室内试验研究 环境工程 专业 2007 级硕士生姓名： 指导教师（姓名、职称）： 摘要 渗透反应 (permeable reaetive barriers，简称PRB)是目前欧美发达国家普遍研究开始初步商业化应用的一项地下水污染修复技术。项技术具有原位处理、处理时效长、同时可处理多种污染物、运行维护费用低等优点。 本论文以721铀矿性废水为研究对象,分别用零价铁粉、膨润土、石灰石和石英砂4种介质,设计了5个PRB反应器对矿山酸性废水的可行性和有效性进行了试验研究。研究成果如下： 1）PRB反应器处理铀矿山堆浸酸性废水是完全可行的混合材料不同配比出水浓度达到国家排放标准国家排放标准）在处理阶段，不同配比的反应材料反应出不同的零价铁石灰石膨润土能中和酸液，Fe3+。pH值升高至4.38时，UO22+会水解成UO2(OH)2、Fe3+转化沉淀 4）在混合材料不同配比中，以零价铁为主要反应介质，石灰石和膨润土为辅助反应介质的PRB，反应条件在Eh2mV，pH8.5，325h内Fe3+的去除率是100%，75h～150h之间U的去除率是99.%，为试验最佳处理效果铀矿山堆浸酸性废水的污染控制PRB技术 关键词：渗透反应格栅；酸性含铀废水；石灰石；零价铁；膨润土 Thesis：Laboratory study of permeable reaetive barrier technology treatment for uranium mine acidic wastewater Speciality: Environmental Engineering Postgraduate: Mentor: Acidic wastewater containing low level uranium mine production in China has an urgent need to solve the problem, to find cost-effective approach to uranium mining on environmental protection and sustainable development is of great significance. The“Permeable reaetive barriers” (PRBs) teehnology,a popular method of in situ remediation of contaminated groundwater widely used reeently in Europe and Ameriea,is a passive treatment teehnology that removes dissolved contaminants from polluted water.The approaeh,compared to the earlier method，is charaetered with in situ remediationgood long-term performanee, many remediable contaminantsands and low costs. In this paper, with acidic wastewater containing low-level uranium from 721 as the research subject, five PRBs reactorswere designed with themixture of zero valent iron(ZVI),active carbon, zeolite as reaction media. The feasibility and effectiveness of treating acidic wastewater containing low-level uranium from 721 by PRBs weretested.The research results are as follows: 1) PRBs reactor acid heap leaching of uranium mine waste water technology is feasible. Hybrid materials with diffe